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- W3011836633 abstract "The synthesis and catalytic applications of trivalent rare-earth metal alkyl complexes have been well developed, but the chemistry of divalent rare-earth metal alkyl complexes lagged much behind. Herein, we report the synthesis, structure, and catalytic applications of a samarium(II) monoalkyl complex supported by a β-diketiminato-based tetradentate ligand, [LSmCH(SiMe3 )2 ] (L=[MeC(NDipp)CHC(Me)NCH2 CH2 N(Me)CH2 CH2 NMe2 ]- , Dipp=2,6-(iPr)2 C6 H3 ). This complex is synthesized by the salt metathesis reaction of samarium iodide [LSm(μ-I)]2 and KCH(SiMe3 )2 in 63 % yield. Its structure is characterized by single-crystal X-ray diffraction, showing a distorted square-pyramid coordination geometry. This samarium(II) monoalkyl complex exhibits high catalytic activity in the hydrosilylation of aryl and methyl-substituted unsymmetrical internal alkynes with secondary hydrosilanes, selectively providing the α-(E) products in high yields." @default.
- W3011836633 created "2020-03-23" @default.
- W3011836633 creator A5010215438 @default.
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- W3011836633 date "2020-04-15" @default.
- W3011836633 modified "2023-10-15" @default.
- W3011836633 title "Samarium(II) Monoalkyl Complex Supported by a β‐Diketiminato‐Based Tetradentate Ligand: Synthesis, Structure, and Catalytic Hydrosilylation of Internal Alkynes" @default.
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- W3011836633 doi "https://doi.org/10.1002/chem.202000342" @default.
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