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• W3011940423 abstract "Abstract Two types of palladium(II)-based metallacalixarenes [ML]2+ and [ML2]2+ have been synthesized through coordination-driven self-assembly from a series of flexible pyridine-bridged diimidazole ligands [2,6-bis((1H-imidazol-1-yl)methyl) pyridine (L1), 2,6-bis((1H-benzo[d]imidazol-1-yl)methyl)pyridine (L2), 2,6-bis((1H-naphtho[2, 3-d]imidazol-1-yl)methyl)pyridine (L3)], with palladium(II)-based building blocks [Pd(BF4)2(M1-BF4) and (tmeda)Pd(NO3)2 (M2-NO3) (tmeda = N,N,N′,N′-tetramethyl-ethylenediamine)]. All complexes were characterized by NMR spectroscopy (1H NMR and 13C NMR), mass spectrometry (CSI-MS, ESI-HRMS) and elemental analysis. The single crystal X-ray diffraction analysis of [M1L22](NO3)2, [M1L32](NO3)2, [M1L32](PF6)2 and [M2L3](NO3)2 further confirmed the uniquely single bowl-shape and double bowl-shape structures. The anion binding properties within the metallacalixarenes as receptors were also investigated by NMR titration experiments in DMSO." @default.
• W3011940423 created "2020-03-23" @default.
• W3011940423 creator A5057495479 @default.
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• W3011940423 date "2021-01-01" @default.
• W3011940423 modified "2023-09-27" @default.
• W3011940423 title "Coordination-driven self-assembly of palladium(II)-based metallacalixarenes as anion receptors using flexible pyridine-bridged diimidazole ligands" @default.
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• W3011940423 doi "https://doi.org/10.1016/j.cclet.2020.03.053" @default.
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