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- W3011996583 abstract "A NHC-promoted cascade reaction between β-methyl enal and dienone is developed for quick access to multicyclic lactone molecules bearing quaternary chiral carbon centers. Our study constitutes the first 1,6-addition of the acylazolium vinyl enolate γ-carbon via NHC catalysis and provides rapid access to complex lactone molecules that are otherwise difficult to prepare. The structurally sophisticated lactone products bearing up to four fused ring structures are afforded in up to quantitative yields with good to excellent enantioselectivities." @default.
- W3011996583 created "2020-03-23" @default.
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- W3011996583 date "2020-03-19" @default.
- W3011996583 modified "2023-10-18" @default.
- W3011996583 title "NHC-Catalyzed Cascade Reaction between β-Methyl Enals and Dienones for Quick Construction of Complex Multicyclic Lactones" @default.
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- W3011996583 doi "https://doi.org/10.1021/acs.orglett.0c00533" @default.
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