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- W3012000378 abstract "Abstract Quinoidal azaacenes with almost pure diradical character ( y= 0.95 to y= 0.99) were synthesized. All compounds exhibit paramagnetic behavior investigated by EPR and NMR spectroscopy, and SQUID measurements, revealing thermally populated triplet states with an extremely low‐energy gap Δ E ST′ of 0.58 to 1.0 kcal mol −1 . The species are persistent in solution (half‐life≈14–21 h) and in the solid state they are stable for weeks." @default.
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- W3012000378 date "2020-04-28" @default.
- W3012000378 modified "2023-09-30" @default.
- W3012000378 title "Quinoidal Azaacenes: 99 % Diradical Character" @default.
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- W3012000378 doi "https://doi.org/10.1002/ange.201915977" @default.
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