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- W3012000404 abstract "Hierarchical ZnFe2O4 yolk-shell spheres (YSs) assembled from primary nanosheets are synthesized via a simple one-step solvothermal method followed by a heat-treatment process. A polypyrrole (PPy) conductive network is formed in-situ on pristine ZnFe2O4 YSs via chemical oxidative polymerization to obtain ZnFe2O4@PPy YSs. Morphological and structural characterization confirms that the conductive PPy coating does not destroy the localized porous microenvironment of pristine ZnFe2O4 with rapid mass transport. The solvothermal reaction time-dependent structure evolution and formation mechanism of ZnFe2O4@PPy YSs have been elucidated. Furthermore, the electrochemical performance of the ZnFe2O4@PPy YSs is assessed and compared with that of pristine ZnFe2O4 YSs. The results reveal that ZnFe2O4@PPy YSs exhibit excellent rate capability and long-term cycling stability, achieving 541.7 mAh g−1 at 5 A g−1 after 1000 cycles. The improved electrochemical performances of ZnFe2O4@PPy YSs are attributed to not only the structural advantages of porous yolk-shell architecture, but also the conductivity enhancement and suppressed volume expansion induced by the PPy layer." @default.
- W3012000404 created "2020-03-23" @default.
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- W3012000404 date "2020-04-01" @default.
- W3012000404 modified "2023-10-16" @default.
- W3012000404 title "Synthesis of porous nanosheet-assembled ZnFe2O4@polypyrrole yolk-shell microspheres as anode materials for high-rate lithium-ion batteries" @default.
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- W3012000404 doi "https://doi.org/10.1016/j.jelechem.2020.114038" @default.
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