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- W3012183691 abstract "Abstract We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones with cyclopentadiene, in which five stereocenters are effectively controlled by a strongly acidic and confined imidodiphosphorimidate catalyst. Our approach provides tricyclic products in excellent stereoselectivity. We also report methods to convert the obtained products into useful intermediates and a computational study that aids in gaining deeper insight into the reaction mechanism and origin of stereoselectivity." @default.
- W3012183691 created "2020-03-23" @default.
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- W3012183691 date "2020-03-11" @default.
- W3012183691 modified "2023-10-14" @default.
- W3012183691 title "Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene" @default.
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- W3012183691 doi "https://doi.org/10.1002/anie.202000307" @default.
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