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- W3012185280 abstract "Goldcatalysis has become one of the fastest growing fields inchemistry, providing new organic transformations and offering excellentchemoselectivities under mild reaction conditions. Methodologicaldevelopments have been driven by wide applicability in the synthesisof complex structures, whereas the mechanistic understanding of Au(III)-mediatedprocesses remains scanty and have become the Achilles’ heelof methodology development. Herein, the systematic investigation ofthe reactivity of bis(pyridine)-ligated Au(III) complexes is presented,based on NMR spectroscopic, X-ray crystallographic, and DFT data.The electron density of pyridines modulates the catalytic activityof Au(III) complexes in propargyl ester cyclopropanation of styrene.To avoid strain induced by a ligand with a nonoptimal nitrogen–nitrogendistance, bidentate bis(pyridine)–Au(III) complexes convertinto dimers. For the first time, bis(pyridine)Au(I) complexes areshown to be catalytically active, with their reactivity being modulatedby strain." @default.
- W3012185280 created "2020-03-23" @default.
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- W3012185280 date "2020-03-13" @default.
- W3012185280 modified "2023-10-05" @default.
- W3012185280 title "CatalyticActivity of trans-Bis(pyridine)goldComplexes" @default.
- W3012185280 doi "https://doi.org/10.1021/jacs.0c01941.s001" @default.
- W3012185280 hasPublicationYear "2020" @default.
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