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- W3012334841 abstract "Functional porous materials show extensive applications in the environment, biology, aerospace, and so on. In this work, the generation of silica foams and functionalization of pore surface were simultaneously realized through an interfacial sol–gel reaction within high internal phase emulsion (HIPE) microreactors, where a hyperbranched polyethoxysiloxane (PEOS) was used as the sole stabilizer for the HIPEs. With various functional substances containing amino, epoxy, and carboxyl groups initially dissolved in the aqueous phase of HIPEs, these functional groups could be grafted onto the pore surface in the process of forming silica foams. Amino-functionalized silica foam showed fast adsorption of sunset yellow, and the adsorption capacity could reach as high as 1213.13 mg/g. Sodium polyacrylate-modified silica foam exhibited good adsorption capacity of cationic dyes and metal ions, e.g., 280.11 mg/g to methylene and 226.24 mg/g to Cu(II). Epoxy-functionalized silica foam particles were confirmed with a pronounced activity at the oil/water interface due to their Janus-like surface, which could be used as Pickering stabilizer. This HIPE-based synthesis strategy for silica foams shows promising future in adsorption, emulsion stabilization, and compatibilization." @default.
- W3012334841 created "2020-03-23" @default.
- W3012334841 creator A5028908278 @default.
- W3012334841 creator A5065735627 @default.
- W3012334841 creator A5087404367 @default.
- W3012334841 creator A5088998781 @default.
- W3012334841 date "2020-03-09" @default.
- W3012334841 modified "2023-10-18" @default.
- W3012334841 title "A Convenient and Versatile Strategy for the Functionalization of Silica Foams Using High Internal Phase Emulsion Templates as Microreactors" @default.
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- W3012334841 doi "https://doi.org/10.1021/acsami.0c01273" @default.
- W3012334841 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32150371" @default.
- W3012334841 hasPublicationYear "2020" @default.
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