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- W3012420104 abstract "Abstract A versatile method for the Suzuki‐Miyaura cross‐coupling of amides using highly active, well‐defined, and air‐stable Pd−phosphine precatalysts is reported. Most notably, the method represents the first example of using practical and operationally‐simple Pd(II)−phosphine precatalysts in the emerging amide bond cross‐coupling manifold. The reactions are efficient at 0.10 mol% loading, furnishing biaryl ketones with high chemoselectivity for N−C(O) bond cleavage. This versatile method enables for the first time to achieve Pd−phosphine‐catalyzed cross‐coupling of amides at ppm loading. This C−N cross‐coupling can be used to efficiently furnish pharmaceutical intermediates by orthogonal Pd‐catalyzed cross‐couplings. We fully expect that operationally‐simple [(PR 3 ) 2 Pd(II)X 2 ] precatalysts as effective triggers for N−C(O) cross‐coupling will be of broad synthetic and catalytic interest. magnified image" @default.
- W3012420104 created "2020-03-23" @default.
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- W3012420104 date "2020-04-03" @default.
- W3012420104 modified "2023-10-14" @default.
- W3012420104 title "Suzuki‐Miyaura Cross‐Coupling of Amides using Well‐Defined, Air‐Stable [(PR <sub>3</sub> ) <sub>2</sub> Pd(II)X <sub>2</sub> ] Precatalysts" @default.
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- W3012420104 doi "https://doi.org/10.1002/adsc.202000122" @default.
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