Matches in SemOpenAlex for { <https://semopenalex.org/work/W3012532993> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W3012532993 endingPage "1331" @default.
- W3012532993 startingPage "1326" @default.
- W3012532993 abstract "This study reported the synthesis of macro-initiator based on microfibers cellulose (MFC) from empty bunches (EFB), which was Ethyl α-bromoisobutyrate. The availability of the hydroxyl group on MFC offered a facile functionalization with Ethyl α-bromoisobutyrate to produce Bromo-ester group on MFC surface (MFC-BiB) that are known to be the excellent initiator for atom transfer radical polymerization (ATRP). As MFC provides only three hydroxyl groups per each unit of glucose with low reactivity, it is crucial to modify MFC with bromide functional groups having reactivity about 10.000 times greater than the hydroxyl group in the MFC. An MFC-BiB macro-initiator was successfully synthesized by homogeneous acetylation of cellulose with Ethyl α-bromoisobutyrate (EBiB) at 40°C. To confirm the performance MFC-BiB as macroinitiator, copolymerization between latex and MFC-BiB was conducted to produce Cellulose-g-latex by ATRP method with bipyridine/CuCl/CuCl2 ligand as a complex catalyst and toluene/water as a mixed solvent. The degree of MFC-BiB substitution was measured by the FTIR method. The grafting copolymers were characterized by H-NMR and FTIR. The results indicated that the degree of substitution of macro-initiator at the ratio of MFC/EBiB of 1:3 and 1:6 were 1.27 and 1.28, respectively. The grafting efficiency of cellulose backbone with latex via ATRP showed a well-controlled grafting reaction at 44.5%." @default.
- W3012532993 created "2020-03-23" @default.
- W3012532993 creator A5007235606 @default.
- W3012532993 creator A5014930018 @default.
- W3012532993 creator A5022910057 @default.
- W3012532993 creator A5023666106 @default.
- W3012532993 date "2020-03-18" @default.
- W3012532993 modified "2023-10-13" @default.
- W3012532993 title "Grafting of cellulose fibers latex by atom transfer radical polymerization" @default.
- W3012532993 cites W1495512096 @default.
- W3012532993 cites W1968021989 @default.
- W3012532993 cites W2009919543 @default.
- W3012532993 cites W2014364661 @default.
- W3012532993 cites W2020301452 @default.
- W3012532993 cites W2062130918 @default.
- W3012532993 cites W2092673507 @default.
- W3012532993 cites W2093792255 @default.
- W3012532993 cites W2094586087 @default.
- W3012532993 cites W2149737621 @default.
- W3012532993 cites W2195278652 @default.
- W3012532993 cites W2900611194 @default.
- W3012532993 cites W4249094517 @default.
- W3012532993 cites W4254477678 @default.
- W3012532993 doi "https://doi.org/10.1080/25740881.2020.1738474" @default.
- W3012532993 hasPublicationYear "2020" @default.
- W3012532993 type Work @default.
- W3012532993 sameAs 3012532993 @default.
- W3012532993 citedByCount "2" @default.
- W3012532993 countsByYear W30125329932021 @default.
- W3012532993 crossrefType "journal-article" @default.
- W3012532993 hasAuthorship W3012532993A5007235606 @default.
- W3012532993 hasAuthorship W3012532993A5014930018 @default.
- W3012532993 hasAuthorship W3012532993A5022910057 @default.
- W3012532993 hasAuthorship W3012532993A5023666106 @default.
- W3012532993 hasConcept C142724271 @default.
- W3012532993 hasConcept C150539798 @default.
- W3012532993 hasConcept C15920480 @default.
- W3012532993 hasConcept C178790620 @default.
- W3012532993 hasConcept C185592680 @default.
- W3012532993 hasConcept C188027245 @default.
- W3012532993 hasConcept C192562407 @default.
- W3012532993 hasConcept C204787440 @default.
- W3012532993 hasConcept C2775937945 @default.
- W3012532993 hasConcept C2776910235 @default.
- W3012532993 hasConcept C2779251873 @default.
- W3012532993 hasConcept C2780995637 @default.
- W3012532993 hasConcept C521977710 @default.
- W3012532993 hasConcept C71924100 @default.
- W3012532993 hasConceptScore W3012532993C142724271 @default.
- W3012532993 hasConceptScore W3012532993C150539798 @default.
- W3012532993 hasConceptScore W3012532993C15920480 @default.
- W3012532993 hasConceptScore W3012532993C178790620 @default.
- W3012532993 hasConceptScore W3012532993C185592680 @default.
- W3012532993 hasConceptScore W3012532993C188027245 @default.
- W3012532993 hasConceptScore W3012532993C192562407 @default.
- W3012532993 hasConceptScore W3012532993C204787440 @default.
- W3012532993 hasConceptScore W3012532993C2775937945 @default.
- W3012532993 hasConceptScore W3012532993C2776910235 @default.
- W3012532993 hasConceptScore W3012532993C2779251873 @default.
- W3012532993 hasConceptScore W3012532993C2780995637 @default.
- W3012532993 hasConceptScore W3012532993C521977710 @default.
- W3012532993 hasConceptScore W3012532993C71924100 @default.
- W3012532993 hasFunder F4320325829 @default.
- W3012532993 hasIssue "12" @default.
- W3012532993 hasLocation W30125329931 @default.
- W3012532993 hasOpenAccess W3012532993 @default.
- W3012532993 hasPrimaryLocation W30125329931 @default.
- W3012532993 hasRelatedWork W1983724339 @default.
- W3012532993 hasRelatedWork W1999322579 @default.
- W3012532993 hasRelatedWork W2057210763 @default.
- W3012532993 hasRelatedWork W2059062708 @default.
- W3012532993 hasRelatedWork W2086727768 @default.
- W3012532993 hasRelatedWork W2147399189 @default.
- W3012532993 hasRelatedWork W2150610502 @default.
- W3012532993 hasRelatedWork W2487138997 @default.
- W3012532993 hasRelatedWork W2607913628 @default.
- W3012532993 hasRelatedWork W2513058969 @default.
- W3012532993 hasVolume "59" @default.
- W3012532993 isParatext "false" @default.
- W3012532993 isRetracted "false" @default.
- W3012532993 magId "3012532993" @default.
- W3012532993 workType "article" @default.