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- W3012606971 abstract "Abstract The molecular structure and conformation of chloroacetaldehyde have been studied by gas-phase electron diffraction at a nozzle temperature of 42°C. The molecules exist as a mixture of two conformers with the chlorine and the oxygen atoms anti and syn to each other. The anti form dominates (94(7)%) at 42°C. The torsional potential for the anti form was found to have a flat and wide minimum with a small hump at the anti position. The results for the distance ( r a ) and angle ( α ) parameters, with estimated uncertainties of 2σ, are: r (CO) = 1.206(3) A, r (CC) = 1.521(5) A, r (CCl) = 1.782(4) A, 〈 r (CH)〉 = 1.093(12) A, ∠CCO = 123.3(6)°, ∠CCCl = 110.4(3)°, ∠CCOH = 112.4(38)°, ∠CCHClH = 110.3(15)° and ∠HCH = 109.5° (assumed)." @default.
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- W3012606971 date "1984-01-10" @default.
- W3012606971 modified "2023-09-26" @default.
- W3012606971 title "ChemInform Abstract: MOLECULAR STRUCTURE AND CONFORMATION OF CHLOROACETALDEHYDE AS DETERMINED BY GAS-PHASE ELECTRON DIFFRACTION" @default.
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- W3012606971 doi "https://doi.org/10.1002/chin.198402061" @default.
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