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• W3012614239 startingPage "5030" @default.
• W3012614239 abstract "The dimetallic boron hydride cluster, (PMe2Ph)4Pt2B10H10 (1-Pt2), is known to reversibly sequester small molecules (e.g., O2, CO, and SO2) across its Pt–Pt cluster vector. Here, we report the very different effect of the addition of nitric oxide (NO) to solutions of (1-Pt2) that prompts the elimination of some of its phosphine ligands and the autofusion of the resultant {(PMe2Ph)xPt2B10H10} units to afford the metallaborane conglomerates (PMe2Ph)8Pt8B40H40 (2-Pt8, 38%) and (PMe2Ph)5Pt4B20H20 (3-Pt4, 34%). Single-crystal X-ray studies of these multicluster assemblies reveal the links between the clusters to be a combination of both Pt–Pt bonds and Pt-μH-B 2-electron, 3-center bonds in (2-Pt8) and Pt-μH-B 2-electron, 3-center bonds in (3-Pt4). For compound (2-Pt8), the cluster assemblage can be effectively reversed by the addition of ethyl isonitrile (EtNC) to afford (EtNC)3(PMe2Ph)2Pt2B10H10 4 in quantitative yield. The compounds were characterized by mass spectrometry, multielement NMR spectroscopy, and single-crystal X-ray diffraction studies." @default.
• W3012614239 created "2020-03-27" @default.
• W3012614239 creator A5047135351 @default.
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• W3012614239 creator A5091708807 @default.
• W3012614239 date "2020-03-24" @default.
• W3012614239 modified "2023-10-16" @default.
• W3012614239 title "A Reversible NO-Triggered Multiple Metallaborane Cluster Fusion by Ligand Expulsion/Addition from (PMe₂Ph)₄Pt₂B₁₀H₁₀ to Afford (PMe₂Ph)₈Pt₈B₄₀H₄₀ and (PMe₂Ph)₅Pt₄B₂₀H₂₀" @default.
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• W3012614239 doi "https://doi.org/10.1021/acs.inorgchem.0c00247" @default.
• W3012614239 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32207620" @default.
• W3012614239 hasPublicationYear "2020" @default.
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