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- W3012783182 abstract "Abstract Infrared spectra of monomeric oxalic acid-h2, -hd and -d2 have been observed using neon matrix-isolation spectroscopy. In addition, spectra of oxalic acid-h2, vapor were obtained using a heated absorption cell with a 10 m pathlength. All IR active fundamentals are assigned for oxalic acid-h2, and -d2, except the low frequency torsion. The spectra are interpreted in terms of the C2h intramolecularly hydrogen bonded model. Two vibrational assignments are discussed; one involves a very large intensity for the v8 + v11 (COH torsion) combination band of oxalic acid-h2. Tentative values for several Raman active fundamentals of oxalic acid-h2 are suggested using possible combination bands. Few fundamentals of oxalic acid-hd correlating with the Raman modes of the symmetric monomers could be observed. A force constant analysis of the by secular block is presented." @default.
- W3012783182 created "2020-03-27" @default.
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- W3012783182 date "1978-10-03" @default.
- W3012783182 modified "2023-09-27" @default.
- W3012783182 title "ChemInform Abstract: INFRARED MATRIX-ISOLATION SPECTRA OF MONOMERIC OXALIC ACID" @default.
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- W3012783182 doi "https://doi.org/10.1002/chin.197840052" @default.
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