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- W3012803105 abstract "Abstract Examination of the carbon-13 NMR spectra and electric dipole moments of isomeric bis(methylthio)benzenes and tetrakis (methylthio)benzenes, 1,2,3- and 1,3,5-tris (methylthio)benzenes, pentakis- and hexakis-(methylthio)benzenes enabled their preferred conformations as a solute to be elucidated. In the preferred conformers, a MeS-group encompassed by two hydrogen atoms is shaped as (45°-twisted) thioanisole, a MeS-group situated near a sulphur atom is identified as 45°-twisted trans -(Me,S), and a MeS-group surrounded by two sulphur atoms is located in a plane perpendicular to the ring. The conformational problem posed by poly(methoxy)benzenes is also briefly discussed." @default.
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- W3012803105 date "1986-08-12" @default.
- W3012803105 modified "2023-09-26" @default.
- W3012803105 title "ChemInform Abstract: Conformational Preferences of Poly(methylthio)benzenes" @default.
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- W3012803105 doi "https://doi.org/10.1002/chin.198632086" @default.
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