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- W3012947650 abstract "Abstract Diphenanthrioctaphyrin(1.1.1.0.1.1.1.0), an expanded carbaporphyrinoid incorporating two phenanthrenylene moieties, exists as two separate, yet interconvertible, locked stereoisomers. These species demonstrate complex dynamic behavior upon protonation, consisting in multiple conformational rearrangements and anion‐binding events. The formation of one of the final dicationic forms is accompanied by the inclusion of a complex anion(s) within the macrocyclic cavity yielding a pseudorotaxane‐like host–guest complex. Protonation with trifluoroacetic or dichloroacetic acids followed by neutralization afforded a conformation‐switching cycle, which involves six structurally different species. Analogous acidification with chiral 10‐camphorsulfonic acid and subsequent neutralization generated one of the free base stereoisomers with enantiomeric excess. Therefore, it was shown that the simple acid‐base chemistry of diphenanthrioctaphyrin can act as stimulus, inducing chirality into the system, allowing for the manipulation of the stereochemical information imprinted into the enantiomers of the macrocycle." @default.
- W3012947650 created "2020-03-27" @default.
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- W3012947650 date "2020-06-18" @default.
- W3012947650 modified "2023-10-10" @default.
- W3012947650 title "Conformation‐Dependent Response to the Protonation of Diphenanthrioctaphyrin(1.1.1.0.1.1.1.0): A Route to Pseudorotaxane‐Like Structures" @default.
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- W3012947650 doi "https://doi.org/10.1002/chem.202000940" @default.
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