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- W3013244088 abstract "Lithium dendrite growth has long been regarded as the main obstacle for the practical usage of lithium metal battery. In this paper, we heat-treat the copper collector at a low temperature to prepare a CuxO (x = 1–2)/Cu composite electrode. The samples heat-treated at 250 °C are mainly composed of Cu2O confirmed by X-ray photoelectron spectroscopy (XPS) analysis, which has the best wettability with propylene carbonate (PC)-based electrolyte. The as-prepared Li–Cu cell (composite electrode) can run more than 150 cycles. However, boric acid additive can prolong the cycle number of Li–Cu cell to more than 300 cycles at a current density of 0.5 mA cm−2 with a Coulombic efficiency larger than 85%. Scanning electron microscopy (SEM) image shows that the Cu2O/Cu composite electrode with boric acid additive in the electrolyte can inhibit the formation of lithium dendrite on the surface of the electrode, and a uniform and dense nano-columnar lithium layer can be obtained even at 5 mA cm−2. The synergistic effect is attributed to the improved interfacial properties for Cu2O/Cu composite collectors when boric acid (BA) is used as additives." @default.
- W3013244088 created "2020-04-03" @default.
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- W3013244088 date "2020-05-01" @default.
- W3013244088 modified "2023-10-08" @default.
- W3013244088 title "The synergistic effect of Cu2O and boric acid forming solid electrolyte interphase layer to restrain the dendritic growth" @default.
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- W3013244088 doi "https://doi.org/10.1016/j.jpowsour.2020.228055" @default.
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