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- W3013322116 abstract "Abstract Synthesis, characterization, and application of Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ materials (where, Ln = La, Pr, Nd, Sm, Gd, Tb, Dy, Er) for the thermochemical conversion of CO 2 reported in this paper. The Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ materials were synthesized by using an ammonium hydroxide-driven co-precipitation method. The derived Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ materials were characterized via powder X-ray diffraction, scanning electron microscope, and electron diffraction spectroscopy. The characterization results indicate the formation of spherically shaped Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ nanostructured particles. As-prepared Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ materials were further tested toward multiple CO 2 splitting cycles by utilizing a thermogravimetric analyzer. The results obtained indicate that all the Ce 0.9 Ln 0.05 Ag 0.05 O 2−δ materials produced higher quantities of O 2 and CO than the previously studied pure CeO 2 and lanthanide-doped ceria materials. Overall, the Ce 0.911 La 0.053 Ag 0.047 O 1.925 showed the maximum redox reactivity in terms of O 2 release (72.2 μmol/g cycle) and CO production (136.6 μmol/g cycle)." @default.
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- W3013322116 date "2020-03-27" @default.
- W3013322116 modified "2023-10-16" @default.
- W3013322116 title "Co-precipitation synthesized nanostructured Ce0.9Ln0.05Ag0.05O2−δ materials for solar thermochemical conversion of CO2 into fuels" @default.
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- W3013322116 doi "https://doi.org/10.1007/s10853-020-04567-w" @default.
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