Matches in SemOpenAlex for { <https://semopenalex.org/work/W3013386506> ?p ?o ?g. }
- W3013386506 endingPage "23" @default.
- W3013386506 startingPage "23" @default.
- W3013386506 abstract "Five cyclometalated Ir(III) tetrazolato complexes functionalised with fatty acid chains (octanoic, palmitic, stearic, palmitoleic, and oleic) have been synthesised. The fatty acids were chosen to evaluate the potential effect of the length and degree of unsaturation on the biological properties of the complexes for use as cellular imaging agents. The complexes were analysed in both organic and aqueous media to determine if the presence and nature of the fatty acid chains had a significant effect on their photophysical properties. The complexes display green–yellow emission in dichloromethane solutions with relatively long excited state decays, within the range 360–393 ns, and quantum yields between 5.4% and 6.7% (from degassed solutions). Temperature-dependent photophysical studies suggest that the emitting excited states of the complexes might be quenched by the thermal population of dark states. In water, the quantum yields drop within the range of 0.5%–2.4%, and the photophysical measurements are influenced by the variable degrees of aggregation. In general, the entire series displayed low cytotoxicity and relatively high photostability, which are favourable attributes in the design of cellular imaging agents. Images of live HeLa cells were obtained for all the complexes, but those functionalised with palmitic and stearic acids had limitations due the lower solubility conferred by the saturated aliphatic chains. The complexes were mainly detected within the endoplasmic reticulum." @default.
- W3013386506 created "2020-04-03" @default.
- W3013386506 creator A5003098392 @default.
- W3013386506 creator A5034883103 @default.
- W3013386506 creator A5041850384 @default.
- W3013386506 creator A5047782731 @default.
- W3013386506 creator A5049954577 @default.
- W3013386506 creator A5061130303 @default.
- W3013386506 creator A5066148381 @default.
- W3013386506 creator A5080074234 @default.
- W3013386506 creator A5089714768 @default.
- W3013386506 date "2020-03-26" @default.
- W3013386506 modified "2023-10-16" @default.
- W3013386506 title "Photophysical and Biological Properties of Iridium Tetrazolato Complexes Functionalised with Fatty Acid Chains" @default.
- W3013386506 cites W1522305543 @default.
- W3013386506 cites W1928594450 @default.
- W3013386506 cites W1964603841 @default.
- W3013386506 cites W1965612889 @default.
- W3013386506 cites W1975570955 @default.
- W3013386506 cites W1978965445 @default.
- W3013386506 cites W1979462927 @default.
- W3013386506 cites W1983271503 @default.
- W3013386506 cites W1983947976 @default.
- W3013386506 cites W1985921689 @default.
- W3013386506 cites W1986451793 @default.
- W3013386506 cites W1987528118 @default.
- W3013386506 cites W1992965219 @default.
- W3013386506 cites W1997107645 @default.
- W3013386506 cites W1998945486 @default.
- W3013386506 cites W2004427611 @default.
- W3013386506 cites W2004602806 @default.
- W3013386506 cites W2008426629 @default.
- W3013386506 cites W2013416758 @default.
- W3013386506 cites W2014892475 @default.
- W3013386506 cites W2028786533 @default.
- W3013386506 cites W2036240062 @default.
- W3013386506 cites W2046366955 @default.
- W3013386506 cites W2048336297 @default.
- W3013386506 cites W2052329392 @default.
- W3013386506 cites W2060517372 @default.
- W3013386506 cites W2066863869 @default.
- W3013386506 cites W2078404952 @default.
- W3013386506 cites W2093130113 @default.
- W3013386506 cites W2106809501 @default.
- W3013386506 cites W2123991513 @default.
- W3013386506 cites W2127393068 @default.
- W3013386506 cites W2128332534 @default.
- W3013386506 cites W2136613938 @default.
- W3013386506 cites W2149077679 @default.
- W3013386506 cites W2154385453 @default.
- W3013386506 cites W2167442923 @default.
- W3013386506 cites W2186953769 @default.
- W3013386506 cites W2209802854 @default.
- W3013386506 cites W2228608853 @default.
- W3013386506 cites W2286236434 @default.
- W3013386506 cites W2314216178 @default.
- W3013386506 cites W2321898980 @default.
- W3013386506 cites W2324625368 @default.
- W3013386506 cites W2328276464 @default.
- W3013386506 cites W2330374780 @default.
- W3013386506 cites W2346114971 @default.
- W3013386506 cites W2346913381 @default.
- W3013386506 cites W2512097229 @default.
- W3013386506 cites W2517217197 @default.
- W3013386506 cites W2522223005 @default.
- W3013386506 cites W2525331624 @default.
- W3013386506 cites W2525592820 @default.
- W3013386506 cites W2743519740 @default.
- W3013386506 cites W2765924843 @default.
- W3013386506 cites W2767488270 @default.
- W3013386506 cites W290576069 @default.
- W3013386506 cites W2908057150 @default.
- W3013386506 cites W2937761843 @default.
- W3013386506 cites W2937974131 @default.
- W3013386506 cites W2952703331 @default.
- W3013386506 cites W2953856050 @default.
- W3013386506 doi "https://doi.org/10.3390/inorganics8040023" @default.
- W3013386506 hasPublicationYear "2020" @default.
- W3013386506 type Work @default.
- W3013386506 sameAs 3013386506 @default.
- W3013386506 citedByCount "4" @default.
- W3013386506 countsByYear W30133865062020 @default.
- W3013386506 countsByYear W30133865062021 @default.
- W3013386506 countsByYear W30133865062022 @default.
- W3013386506 crossrefType "journal-article" @default.
- W3013386506 hasAuthorship W3013386506A5003098392 @default.
- W3013386506 hasAuthorship W3013386506A5034883103 @default.
- W3013386506 hasAuthorship W3013386506A5041850384 @default.
- W3013386506 hasAuthorship W3013386506A5047782731 @default.
- W3013386506 hasAuthorship W3013386506A5049954577 @default.
- W3013386506 hasAuthorship W3013386506A5061130303 @default.
- W3013386506 hasAuthorship W3013386506A5066148381 @default.
- W3013386506 hasAuthorship W3013386506A5080074234 @default.
- W3013386506 hasAuthorship W3013386506A5089714768 @default.
- W3013386506 hasBestOaLocation W30133865061 @default.
- W3013386506 hasConcept C121332964 @default.
- W3013386506 hasConcept C144024400 @default.
- W3013386506 hasConcept C149923435 @default.