FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3013460969> ?p ?o ?g. }

• W3013460969 endingPage "3025" @default.
• W3013460969 startingPage "3019" @default.
• W3013460969 abstract "Reactive nitrogen species (RNS), along with reactive oxygen species (ROS), are significant products from radiolysis in solution. While much research has been focused on biological systems, these species are also important products in the autoradiolysis that occurs in nuclear waste. Here, we determine the correlation between solution constituents, particularly nitrite, and radical products in highly alkaline solutions relevant to liquid waste. Because these radicals tend to be very short-lived, we employ spin trapping in conjunction with electron paramagnetic resonance (EPR) to detect them and quantify their production. Most spin traps do not function in these conditions (>1 M NaOH); however, nitroalkanes such as nitromethane will act as spin traps in their aci form, which is dominant at high pH. To restrict the products to those originating from nitrite, we use 280–480 nm UV light to generate radicals, avoiding products from the photolysis of water. Under these circumstances, nitric oxide, nitrite radicals, and hydroxyl radicals are detected, and the trends with the concentration of the constituents of the solutions are tracked. These include nitrite, nitrate, hydroxide, and carbonate. We find that, while the equilibrium shifts with increasing pH from hydroxyl radicals to the more slowly reacting oxide radicals, the production of nitrite radicals does not decrease." @default.
• W3013460969 created "2020-04-03" @default.
• W3013460969 creator A5017152024 @default.
• W3013460969 creator A5035348848 @default.
• W3013460969 creator A5040558103 @default.
• W3013460969 creator A5057565012 @default.
• W3013460969 creator A5062626413 @default.
• W3013460969 creator A5070797697 @default.
• W3013460969 creator A5088380075 @default.
• W3013460969 date "2020-03-30" @default.
• W3013460969 modified "2023-09-25" @default.
• W3013460969 title "Evolution of Radicals from the Photolysis of High Ionic Strength Alkaline Nitrite Solutions" @default.
• W3013460969 cites W1483340608 @default.
• W3013460969 cites W1555228407 @default.
• W3013460969 cites W158291190 @default.
• W3013460969 cites W1926950498 @default.
• W3013460969 cites W1975114702 @default.
• W3013460969 cites W1977175213 @default.
• W3013460969 cites W1987389448 @default.
• W3013460969 cites W1987571392 @default.
• W3013460969 cites W1996914014 @default.
• W3013460969 cites W2008629768 @default.
• W3013460969 cites W2017092542 @default.
• W3013460969 cites W2022574774 @default.
• W3013460969 cites W2025566216 @default.
• W3013460969 cites W2031256793 @default.
• W3013460969 cites W2031535721 @default.
• W3013460969 cites W2039241150 @default.
• W3013460969 cites W2040497971 @default.
• W3013460969 cites W2047426870 @default.
• W3013460969 cites W2047438255 @default.
• W3013460969 cites W2049510271 @default.
• W3013460969 cites W2056227360 @default.
• W3013460969 cites W2056979802 @default.
• W3013460969 cites W2060364125 @default.
• W3013460969 cites W2070599733 @default.
• W3013460969 cites W2076055404 @default.
• W3013460969 cites W2097970615 @default.
• W3013460969 cites W2323645497 @default.
• W3013460969 cites W2328665354 @default.
• W3013460969 cites W2774973307 @default.
• W3013460969 cites W4236912041 @default.
• W3013460969 cites W4256251957 @default.
• W3013460969 doi "https://doi.org/10.1021/acs.jpca.9b11438" @default.
• W3013460969 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32223163" @default.
• W3013460969 hasPublicationYear "2020" @default.
• W3013460969 type Work @default.
• W3013460969 sameAs 3013460969 @default.
• W3013460969 citedByCount "3" @default.
• W3013460969 countsByYear W30134609692020 @default.
• W3013460969 countsByYear W30134609692021 @default.
• W3013460969 countsByYear W30134609692023 @default.
• W3013460969 crossrefType "journal-article" @default.
• W3013460969 hasAuthorship W3013460969A5017152024 @default.
• W3013460969 hasAuthorship W3013460969A5035348848 @default.
• W3013460969 hasAuthorship W3013460969A5040558103 @default.
• W3013460969 hasAuthorship W3013460969A5057565012 @default.
• W3013460969 hasAuthorship W3013460969A5062626413 @default.
• W3013460969 hasAuthorship W3013460969A5070797697 @default.
• W3013460969 hasAuthorship W3013460969A5088380075 @default.
• W3013460969 hasBestOaLocation W30134609692 @default.
• W3013460969 hasConcept C121332964 @default.
• W3013460969 hasConcept C139066938 @default.
• W3013460969 hasConcept C178790620 @default.
• W3013460969 hasConcept C179104552 @default.
• W3013460969 hasConcept C185592680 @default.
• W3013460969 hasConcept C187961010 @default.
• W3013460969 hasConcept C2776179834 @default.
• W3013460969 hasConcept C2776384668 @default.
• W3013460969 hasConcept C2776778087 @default.
• W3013460969 hasConcept C2778815226 @default.
• W3013460969 hasConcept C46141821 @default.
• W3013460969 hasConcept C54582936 @default.
• W3013460969 hasConcept C66887884 @default.
• W3013460969 hasConcept C75473681 @default.
• W3013460969 hasConceptScore W3013460969C121332964 @default.
• W3013460969 hasConceptScore W3013460969C139066938 @default.
• W3013460969 hasConceptScore W3013460969C178790620 @default.
• W3013460969 hasConceptScore W3013460969C179104552 @default.
• W3013460969 hasConceptScore W3013460969C185592680 @default.
• W3013460969 hasConceptScore W3013460969C187961010 @default.
• W3013460969 hasConceptScore W3013460969C2776179834 @default.
• W3013460969 hasConceptScore W3013460969C2776384668 @default.
• W3013460969 hasConceptScore W3013460969C2776778087 @default.
• W3013460969 hasConceptScore W3013460969C2778815226 @default.
• W3013460969 hasConceptScore W3013460969C46141821 @default.
• W3013460969 hasConceptScore W3013460969C54582936 @default.
• W3013460969 hasConceptScore W3013460969C66887884 @default.
• W3013460969 hasConceptScore W3013460969C75473681 @default.
• W3013460969 hasFunder F4320337547 @default.
• W3013460969 hasIssue "16" @default.
• W3013460969 hasLocation W30134609691 @default.
• W3013460969 hasLocation W30134609692 @default.
• W3013460969 hasLocation W30134609693 @default.
• W3013460969 hasOpenAccess W3013460969 @default.
• W3013460969 hasPrimaryLocation W30134609691 @default.
• W3013460969 hasRelatedWork W1986445704 @default.
• W3013460969 hasRelatedWork W1996893459 @default.

• next