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- W3013918494 abstract "Abstract Organic compounds as electrode materials can contribute to sustainability because they are nontoxic and environmentally abundant. The working mechanism during charge–discharge for reported organic compounds as electrode materials is yet to be completely understood. In this study, the structural behavior of 2,5‐dimethoxy‐1,4‐benzoquinone (DMBQ) during charge—discharge is investigated by using NMR spectroscopy, energy‐dispersive X‐ray spectroscopy, magnetic measurements, operando Raman spectroscopy, and operando X‐ray diffraction. For both lithium and sodium systems, DMBQ works as a cathode accompanied with the insertion and deinsertion of Li and Na ions during charge—discharge processes. The DMBQ sample is found to be in two‐phase coexistence state at the higher voltage plateau, and the radical monoanion and dianion phases have no long‐distance ordering. These structures reversibly change into the original neutral phase with long‐distance ordering. These techniques can show the charge–discharge mechanism and the factors that determine the deterioration of organic batteries, thus guiding the design of future high‐performance organic batteries." @default.
- W3013918494 created "2020-04-03" @default.
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- W3013918494 date "2020-04-28" @default.
- W3013918494 modified "2023-10-18" @default.
- W3013918494 title "Analytical Measurements to Elucidate Structural Behavior of 2,5‐Dimethoxy‐1,4‐benzoquinone During Charge and Discharge" @default.
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- W3013918494 doi "https://doi.org/10.1002/cssc.201903575" @default.
- W3013918494 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7317396" @default.
- W3013918494 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32220113" @default.
- W3013918494 hasPublicationYear "2020" @default.
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