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- W3014336411 abstract "Abstract Three dinuclear cobalt(II) compounds with different fluoro-substituted benzoate ligands, named as [Co2(3,4-dfba)4(bpp)2]n (1), [Co2(3-fba)4(bpp)2]n (2) and {[Co2(2,4-dfba)4(bpp)2(H2O)]·(bpp)(H2O)}n (3) (3,4-Hdfba = 3,4-difluorobenzoic acid, 3-Hfba = 3-fluorobenzoic acid, 2,4-Hdfba = 2,4-difluorobenzoic acid, bpp = 1,3-bis(4-pyridyl)propane), have been successfully synthesized. In all compounds, Co(II) centers feature hexa-coordinated environments with distorted octahedrons. Among them, compounds 1 and 2 are isomorphic which perform three-dimensional (3D) network, whereas 3 displays a 2D layer structure. This modulation leads to different antiferromagnetic interactions between the metal ions (J1 = −6.43 cm−1, J2 = −2.28 cm−1 for 1, J1 = −19.44 cm−1, J2 = −6.08 cm−1 for 2, J = −12.65 cm−1 for 3)." @default.
- W3014336411 created "2020-04-10" @default.
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- W3014336411 date "2020-06-01" @default.
- W3014336411 modified "2023-10-13" @default.
- W3014336411 title "Three new cobalt(II) coordination polymers based on 1,3-bis(4-pyridyl)propane: Syntheses, structures and magnetic properties" @default.
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- W3014336411 doi "https://doi.org/10.1016/j.inoche.2020.107912" @default.
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