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- W3014467195 abstract "Abstract In this study we synthesized Pd(0) nanoparticles with nearly 20 nm size using p(3-Sulfopropyl acrylate) (p(SPA)) hydrogel as support material. Pd@p(SPA) containing Pd (0) nanoparticles with nearly homogeneous distribution was characterized structurally with TEM, XRD, XPS and elemental mapping. The Pd@p(SPA) was used for the catalytic hydrolysis reaction of ethylenediamine bisborane (EDAB). A series of reactions were completed by changing parameters like the catalyst amount, EDAB concentration and temperature. The Pd@p(SPA) was determined to have turnover frequency (TOF) value of 354 mol H2.molPd(0)−1.h−1 at 30 °C for the hydrolysis reaction of EDAB. The activation parameters for the reaction were Ea = 67.79 kJmol-1, ΔH# = 65.15 kJmol-1 and ΔS# = -103.26 Jmol−1K−1. Pd@p(SPA) also had excellent reusability for the hydrolysis of EDAB. Even after ten reaction cycles, Pd@p(SPA) had 87% catalytic activity. At the same time after four months of storage in an aqueous medium, Pd@p(SPA) still had 100% catalytic activity." @default.
- W3014467195 created "2020-04-10" @default.
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- W3014467195 date "2020-08-01" @default.
- W3014467195 modified "2023-10-06" @default.
- W3014467195 title "Pd nanoreactors with excellent catalytic activity supported in p(SPA) hydrogel networks for hydrogen production from ethylenediamine bisborane" @default.
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- W3014467195 doi "https://doi.org/10.1016/j.renene.2020.03.177" @default.
- W3014467195 hasPublicationYear "2020" @default.
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