Matches in SemOpenAlex for { <https://semopenalex.org/work/W3014597612> ?p ?o ?g. }
- W3014597612 endingPage "122425" @default.
- W3014597612 startingPage "122425" @default.
- W3014597612 abstract "Polybutene-1 (PB-1) exhibits excellent mechanical properties, while an unavoidable polymorphic transition from a metastable form II to the stable form I occurs after solidification from the molten state. This transition goes along with a deformation of the crystal lattice corresponding to a lateral shrinkage and normal elongation of about 20% and 12%, respectively. Here we study the semicrystalline morphology before and after the transition using small-angle X-ray scattering (SAXS) and differential scanning calorimeter (DSC). Scattering curves of samples with form II crystals could be well described by a model of layer-like stacked lamellar crystals. However, the scattering signal of form I samples showed additional scattering contributions at higher scattering vectors, indicating the generation of fine structures during the transition, much smaller than lamellar long spacing. The lamellar thickness increased less than the factor of 1.12, expected from the elongation of the lattice. The results indicate that the large lamellar crystals split up into blocks during the transition creating new interstitial spaces within the lamellae. This process is caused by the fact that the laterally extended lamella of form II cannot shrink as a whole due to the connectivity of the chains emanating from the crystals and due to possible overcrowding of the chain segments at the crystalline/amorphous interfaces." @default.
- W3014597612 created "2020-04-10" @default.
- W3014597612 creator A5003623313 @default.
- W3014597612 creator A5010616574 @default.
- W3014597612 creator A5041873075 @default.
- W3014597612 creator A5052350757 @default.
- W3014597612 creator A5055798245 @default.
- W3014597612 creator A5081935806 @default.
- W3014597612 creator A5088875686 @default.
- W3014597612 date "2020-05-01" @default.
- W3014597612 modified "2023-10-16" @default.
- W3014597612 title "Hierarchical structure of polybutene-1 in crystal blocks resulting from the form II to I solid-to-solid transition as revealed by small-angle X-ray scattering" @default.
- W3014597612 cites W1542524500 @default.
- W3014597612 cites W1809783009 @default.
- W3014597612 cites W1810144817 @default.
- W3014597612 cites W1967442905 @default.
- W3014597612 cites W1970919415 @default.
- W3014597612 cites W1973360904 @default.
- W3014597612 cites W1974428886 @default.
- W3014597612 cites W1975554011 @default.
- W3014597612 cites W1979757018 @default.
- W3014597612 cites W1980801873 @default.
- W3014597612 cites W1980867291 @default.
- W3014597612 cites W1982769346 @default.
- W3014597612 cites W1984334193 @default.
- W3014597612 cites W1985524340 @default.
- W3014597612 cites W1987517227 @default.
- W3014597612 cites W1988752348 @default.
- W3014597612 cites W1992037938 @default.
- W3014597612 cites W1998569357 @default.
- W3014597612 cites W1999374837 @default.
- W3014597612 cites W2000675235 @default.
- W3014597612 cites W2003994478 @default.
- W3014597612 cites W2006044352 @default.
- W3014597612 cites W2010885525 @default.
- W3014597612 cites W2011177051 @default.
- W3014597612 cites W2012869269 @default.
- W3014597612 cites W2013138119 @default.
- W3014597612 cites W2013760906 @default.
- W3014597612 cites W2016900837 @default.
- W3014597612 cites W2024435414 @default.
- W3014597612 cites W2025087206 @default.
- W3014597612 cites W2036152656 @default.
- W3014597612 cites W2037723057 @default.
- W3014597612 cites W2039950968 @default.
- W3014597612 cites W2040312159 @default.
- W3014597612 cites W2044061816 @default.
- W3014597612 cites W2045467597 @default.
- W3014597612 cites W2046248966 @default.
- W3014597612 cites W2047280476 @default.
- W3014597612 cites W2051678022 @default.
- W3014597612 cites W2052096258 @default.
- W3014597612 cites W2061737480 @default.
- W3014597612 cites W2065897391 @default.
- W3014597612 cites W2071436731 @default.
- W3014597612 cites W2074319906 @default.
- W3014597612 cites W2078962987 @default.
- W3014597612 cites W2079912687 @default.
- W3014597612 cites W2089262225 @default.
- W3014597612 cites W2091035407 @default.
- W3014597612 cites W2106898600 @default.
- W3014597612 cites W2111353140 @default.
- W3014597612 cites W2115515297 @default.
- W3014597612 cites W2129304704 @default.
- W3014597612 cites W2140981013 @default.
- W3014597612 cites W2142889103 @default.
- W3014597612 cites W2149856144 @default.
- W3014597612 cites W2151017380 @default.
- W3014597612 cites W2314980097 @default.
- W3014597612 cites W2321434330 @default.
- W3014597612 cites W2322399988 @default.
- W3014597612 cites W2328385303 @default.
- W3014597612 cites W2345500256 @default.
- W3014597612 cites W2470260866 @default.
- W3014597612 cites W2471232367 @default.
- W3014597612 cites W2580215152 @default.
- W3014597612 cites W2610856665 @default.
- W3014597612 cites W2736030975 @default.
- W3014597612 cites W2773765142 @default.
- W3014597612 cites W2782458581 @default.
- W3014597612 cites W2790403792 @default.
- W3014597612 cites W2791486223 @default.
- W3014597612 cites W2793372226 @default.
- W3014597612 cites W2801517522 @default.
- W3014597612 cites W2896866224 @default.
- W3014597612 cites W2897481336 @default.
- W3014597612 cites W2987641222 @default.
- W3014597612 cites W4233064284 @default.
- W3014597612 cites W4237507296 @default.
- W3014597612 doi "https://doi.org/10.1016/j.polymer.2020.122425" @default.
- W3014597612 hasPublicationYear "2020" @default.
- W3014597612 type Work @default.
- W3014597612 sameAs 3014597612 @default.
- W3014597612 citedByCount "22" @default.
- W3014597612 countsByYear W30145976122020 @default.
- W3014597612 countsByYear W30145976122021 @default.
- W3014597612 countsByYear W30145976122022 @default.
- W3014597612 countsByYear W30145976122023 @default.