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- W3014611642 abstract "We have synthesized a series of transition metal compounds [M(L)2(H2O)2] (M = Co (1), Ni (2), and Cu (3)) by using the 4-amino-1,2,4-triazole Schiff-base ligand via the hydrothermal methods. They are all mononuclear compounds with the octahedral geometry. Direct-current magnetic and HF-EPR measurements were combined to reveal the negative D values (-28.78 cm-1, -10.79 cm-1) of complexes 1 and 2, showing the easy-axis magnetic anisotropies of compounds 1 and 2. Applying a dc field of 800 Oe at 2.0 K, the slow magnetic relaxation effects were observed in compound 1, which is a remarkable feature of single-ion magnets." @default.
- W3014611642 created "2020-04-10" @default.
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- W3014611642 date "2020-01-01" @default.
- W3014611642 modified "2023-10-16" @default.
- W3014611642 title "Synthesis, crystal structures, HF-EPR, and magnetic properties of six-coordinate transition metal (Co, Ni, and Cu) compounds with a 4-amino-1,2,4-triazole Schiff-base ligand" @default.
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- W3014611642 doi "https://doi.org/10.1039/c9ra10851c" @default.
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