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- W3014626235 abstract "This report describes the first example of the generation of composition‐defined bimetallic Mo‐Pt sub‐nanosized particles. UV/Vis titration experiments were carried out in order to control the mole ratio of Mo and Pt using a phenylazomethine dendrimer as a molecular template. After supporting the assemblies onto the carbon support, reductive calcination under an atmosphere of H 2 afforded the samples of sub‐nanosized particles supported on the carbon ( Mo 4 Pt 8 and Mo 4 Pt 24 ). The Mo‐Pt particles with sub nano‐size were confirmed by scanning transmission electron microscopy with energy‐dispersive X‐ray spectrometry, and the size distribution ( Mo 4 Pt 8 : 0.9 ± 0.2 nm; Mo 4 Pt 24 : 1.0 ± 0.2 nm) and the Mo/Pt mole ratio ( Mo 4 Pt 8 : 1/1.8 ± 0.2, Mo 4 Pt 24 : 1/5.2 ± 0.4) were revealed, respectively. Moreover, it was suggested that the interactions between Mo and Pt lead increase of a thermal stability of the Mo‐Pt sub‐nanosized particles." @default.
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- W3014626235 date "2020-04-30" @default.
- W3014626235 modified "2023-10-10" @default.
- W3014626235 title "Composition‐Defined Bimetallic Mo‐Pt Sub‐Nanosized Particles" @default.
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- W3014626235 doi "https://doi.org/10.1002/ejic.202000055" @default.
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