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- W3014672308 abstract "Abstract Organic materials receive increasing attention as environmentally benign and sustainable electrode‐active materials. We present a conducting redox polymer (CRP) based on poly(3,4‐ethylenedioxythiophene) with naphthoquinone pendant group, which is formed from a stable suspension of a trimeric precursor and an oxoammonium cation as oxidant. This suspension allows us to easily coat the polymer onto a current collector, opening up use of roll‐to‐roll processing or ink‐jet printing for electrode preparation. The CRP showed a full capacity of 76 mAh g −1 even at a high C rate of 100 C in acidic aqueous electrolyte. These properties make the CRP a promising candidate as anode‐active material; a polymer–air secondary battery was fabricated with the CRP as anode, a conventional Pt/C catalyst as cathode, and sulfuric acid aqueous solution as electrolyte. This battery yielded a discharge voltage of 0.50 V and showed good cycling stability with 97 % capacity retention after 100 cycles and high rate capabilities up to 20 C." @default.
- W3014672308 created "2020-04-10" @default.
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- W3014672308 date "2020-04-27" @default.
- W3014672308 modified "2023-10-18" @default.
- W3014672308 title "Conducting Redox Polymer as a Robust Organic Electrode‐Active Material in Acidic Aqueous Electrolyte towards Polymer–Air Secondary Batteries" @default.
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- W3014672308 doi "https://doi.org/10.1002/cssc.202000627" @default.
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