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- W3014687862 abstract "Alstoniascholarines T (1) and U (2), two novel monoterpenoid indole alkaloids from Alstonia scholaris, enabled an unexpected deuteration via activation of the sp2 CH bond without any catalysts under room temperature. Structurally, alkaloid 1 represented the rare nor-C17 strychnan indole, and compound 2 possessing highly modified strychnan skeleton with an additional furan ring between C-16/19. This finding presented the detailed description of natural products with sp2 CH self-activation and deuteration, which may shed a light on the CH functionalization blocked by the expensive metal catalysts and/or rather harsh reaction conditions." @default.
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- W3014687862 date "2020-05-01" @default.
- W3014687862 modified "2023-09-23" @default.
- W3014687862 title "Indole alkaloids with self-activated sp2 C H bond from Alstonia scholaris" @default.
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- W3014687862 doi "https://doi.org/10.1016/j.tetlet.2020.151894" @default.
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