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- W3014744892 abstract "Abstract A 1:1 mixture of pseudoenantiomer ethynylhelicene ( P )‐pentamer and ( M )‐tetramer in toluene formed hetero‐double‐helix and their self‐assembled gels. Kinetic analysis under isothermal conditions showed a complex nonlinear nature with regard to temperature changes. At 60°C, sigmoidal kinetics were observed, which disappeared after seeding with the self‐assembled gels. These findings indicate the involvement of self‐catalytic reaction I, in which a hetero‐double‐helix catalyzes the reaction to form a hetero‐double‐helix from random‐coils. At 20°C, stairwise biphasic kinetics were observed, which disappeared after seeding. This phenomenon was explained by the involvement of two reactions with sigmoidal kinetics, namely, the formation of self‐assembled gel I from hetero‐double‐helix by self‐catalytic reaction II and the formation of self‐assembled gel II by self‐catalytic reaction III. Constant‐rate temperature change experiments between 90 and 5°C showed nonsigmoidal thermal hysteresis in accordance with the involvement of sequential self‐catalytic reactions with different reaction rates." @default.
- W3014744892 created "2020-04-10" @default.
- W3014744892 creator A5031684966 @default.
- W3014744892 creator A5041245644 @default.
- W3014744892 date "2020-04-06" @default.
- W3014744892 modified "2023-10-09" @default.
- W3014744892 title "Sequential self‐catalytic reactions in the formation of hetero‐double‐helix and their self‐assembled gels by pseudoenantiomer mixtures of ethynylhelicene oligomers" @default.
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- W3014744892 doi "https://doi.org/10.1002/chir.23224" @default.
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