Matches in SemOpenAlex for { <https://semopenalex.org/work/W3014978620> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W3014978620 abstract "We present a theoretical analysis of the current–voltage characteristics of electrolytic cells using their electrical impedance response to a simple periodic external voltage of small amplitude. The examined cell is a thin-film electrolyte (solid, liquid, or gel) sandwiched between flat electrodes at which Ohmic conduction or adsorption–desorption phenomena occur. The basic equations of the Poisson–Nernst–Planck (PNP) model are analytically solved for the case of two diffusing mobile ions (ambipolar diffusion), yielding the charge densities in thermal equilibrium and the profile of the electric potential across the sample. Proper boundary conditions permit us to explore the influence of blocking, Ohmic and adsorbing-desorbing electrodes on the final I(V) curves. Remarkable, it is possible to establish an equivalence between the Ohmic and adsorption–desorption boundary conditions for a general set of physically relevant values of the parameters characterizing the electrodes. This equivalence is a natural way to further incorporate a frequency dispersion caused by the surfaces on the whole response of the cell. This makes the approach well-tailored to investigate the role of the different diffusion coefficients for cations and anions as well as the surface effects on the voltammetry measurements in insulators containing ionic impurities." @default.
- W3014978620 created "2020-04-10" @default.
- W3014978620 creator A5006098704 @default.
- W3014978620 creator A5024117597 @default.
- W3014978620 creator A5060481487 @default.
- W3014978620 creator A5086545098 @default.
- W3014978620 date "2020-01-01" @default.
- W3014978620 modified "2023-09-28" @default.
- W3014978620 title "Current–Voltage Characteristics and Impedance Spectroscopy: Surface Conduction and Adsorption–Desorption Effects in Electrolytic Cells" @default.
- W3014978620 hasPublicationYear "2020" @default.
- W3014978620 type Work @default.
- W3014978620 sameAs 3014978620 @default.
- W3014978620 citedByCount "0" @default.
- W3014978620 crossrefType "journal-article" @default.
- W3014978620 hasAuthorship W3014978620A5006098704 @default.
- W3014978620 hasAuthorship W3014978620A5024117597 @default.
- W3014978620 hasAuthorship W3014978620A5060481487 @default.
- W3014978620 hasAuthorship W3014978620A5086545098 @default.
- W3014978620 hasConcept C113196181 @default.
- W3014978620 hasConcept C121332964 @default.
- W3014978620 hasConcept C138230450 @default.
- W3014978620 hasConcept C147789679 @default.
- W3014978620 hasConcept C150394285 @default.
- W3014978620 hasConcept C162711632 @default.
- W3014978620 hasConcept C172100665 @default.
- W3014978620 hasConcept C17525397 @default.
- W3014978620 hasConcept C185592680 @default.
- W3014978620 hasConcept C43617362 @default.
- W3014978620 hasConcept C68801617 @default.
- W3014978620 hasConcept C97355855 @default.
- W3014978620 hasConceptScore W3014978620C113196181 @default.
- W3014978620 hasConceptScore W3014978620C121332964 @default.
- W3014978620 hasConceptScore W3014978620C138230450 @default.
- W3014978620 hasConceptScore W3014978620C147789679 @default.
- W3014978620 hasConceptScore W3014978620C150394285 @default.
- W3014978620 hasConceptScore W3014978620C162711632 @default.
- W3014978620 hasConceptScore W3014978620C172100665 @default.
- W3014978620 hasConceptScore W3014978620C17525397 @default.
- W3014978620 hasConceptScore W3014978620C185592680 @default.
- W3014978620 hasConceptScore W3014978620C43617362 @default.
- W3014978620 hasConceptScore W3014978620C68801617 @default.
- W3014978620 hasConceptScore W3014978620C97355855 @default.
- W3014978620 hasLocation W30149786201 @default.
- W3014978620 hasOpenAccess W3014978620 @default.
- W3014978620 hasPrimaryLocation W30149786201 @default.
- W3014978620 hasRelatedWork W1172941055 @default.
- W3014978620 hasRelatedWork W1544367928 @default.
- W3014978620 hasRelatedWork W2018203118 @default.
- W3014978620 hasRelatedWork W2020545263 @default.
- W3014978620 hasRelatedWork W2030089041 @default.
- W3014978620 hasRelatedWork W2043070492 @default.
- W3014978620 hasRelatedWork W2051792191 @default.
- W3014978620 hasRelatedWork W2063054921 @default.
- W3014978620 hasRelatedWork W2146070336 @default.
- W3014978620 hasRelatedWork W2255723434 @default.
- W3014978620 hasRelatedWork W2291682316 @default.
- W3014978620 hasRelatedWork W2509373664 @default.
- W3014978620 hasRelatedWork W2515164856 @default.
- W3014978620 hasRelatedWork W2588249388 @default.
- W3014978620 hasRelatedWork W2766297318 @default.
- W3014978620 hasRelatedWork W2790237135 @default.
- W3014978620 hasRelatedWork W2952364629 @default.
- W3014978620 hasRelatedWork W3163564158 @default.
- W3014978620 hasRelatedWork W572071522 @default.
- W3014978620 hasRelatedWork W973199268 @default.
- W3014978620 isParatext "false" @default.
- W3014978620 isRetracted "false" @default.
- W3014978620 magId "3014978620" @default.
- W3014978620 workType "article" @default.