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• W3014979433 startingPage "11835" @default.
• W3014979433 abstract "We have added the {ReIV X5 }- (X=Br, Cl) synthon to a pocket-based ligand to provide supramolecular design using halogen⋅⋅⋅halogen interactions within an FeIII system that has the potential to undergo spin crossover (SCO). By removing the solvent from the crystal lattice, we switch on halogen⋅⋅⋅halogen interactions between neighboring molecules, providing a supramolecular cooperative pathway for SCO. Furthermore, changes to the halogen-based interaction allow us to modify the temperature and nature of the SCO event." @default.
• W3014979433 created "2020-04-10" @default.
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• W3014979433 date "2020-08-13" @default.
• W3014979433 modified "2023-10-14" @default.
• W3014979433 title "The First Use of a ReX₅ Synthon to Modulate Fe^III Spin Crossover via Supramolecular Halogen⋅⋅⋅Halogen Interactions" @default.
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• W3014979433 doi "https://doi.org/10.1002/chem.202001668" @default.
• W3014979433 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7540276" @default.
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