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• W3015104966 abstract "α-Aryl oxindoles are accessed from isatin via a two-step procedure involving a phospha-Brook rearrangement and a Friedel-Crafts alkylation in a one-pot procedure. The use of 1,1,1,3,3,3-hexafluoro-2-propanol as solvent significantly extended the reaction substrate scope to include relatively less electron-rich arenes including benzene. This new alkylation method is fast and straightforward and allows for the direct introduction of the oxindole moiety onto a range of aromatic compounds including phenols. Additionally, the application of arylated products was shown in decarboxylative asymmetric allylation and protonation." @default.
• W3015104966 created "2020-04-10" @default.
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• W3015104966 date "2020-04-07" @default.
• W3015104966 modified "2023-10-17" @default.
• W3015104966 title "Synthesis of α-Aryl Oxindoles by Friedel–Crafts Alkylation of Arenes" @default.
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• W3015104966 doi "https://doi.org/10.1021/acs.joc.0c00370" @default.
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