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- W3015108424 endingPage "13567" @default.
- W3015108424 startingPage "13543" @default.
- W3015108424 abstract "Abstract Bifunctional unsaturated reagents designed to undergo palladium‐catalyzed cross‐coupling reactions with complementary polyenyl connective fragments are highly useful for the undoubtedly challenging synthesis of polyenes. The current toolkit of building blocks for the bidirectional formation of Csp 2 −Csp 2 single bonds of polyenes includes homo‐bisfunctionalized reagents with equal or unequal reactivity (due to steric and/or electronic factors), and hetero‐bisfunctionalized counterparts containing either two different nucleophiles, two electrophiles or one of these functionalities and a latent nucleophile that can be unmasked when desired. The combination of these bifunctional linchpin reagents using tactics that modulate the reactivity of each terminus in order to achieve the required connection have streamlined the synthesis of polyenes of great complexity using (iterative) cross‐coupling methods for Csp 2 −Csp 2 bond formation. Reaction conditions for the Pd‐catalyzed cross‐coupling reactions are mild and functional‐group‐tolerant, and therefore these protocols allow to construct the polyene structures using shorter unsaturated reactants with the desired geometries, since in general the products preserve the stereochemical information of the connected cross‐coupling partners." @default.
- W3015108424 created "2020-04-10" @default.
- W3015108424 creator A5014308020 @default.
- W3015108424 creator A5018134771 @default.
- W3015108424 creator A5054167423 @default.
- W3015108424 creator A5079458615 @default.
- W3015108424 creator A5081734422 @default.
- W3015108424 date "2020-09-17" @default.
- W3015108424 modified "2023-09-26" @default.
- W3015108424 title "Synthesis of Symmetrical and Nonsymmetrical Polyenes by Iterative and Bidirectional Palladium‐Catalyzed Cross‐Coupling Reactions" @default.
- W3015108424 cites W1121504489 @default.
- W3015108424 cites W1561311795 @default.
- W3015108424 cites W1747598905 @default.
- W3015108424 cites W1964136064 @default.
- W3015108424 cites W1965815220 @default.
- W3015108424 cites W1968290497 @default.
- W3015108424 cites W1968789723 @default.
- W3015108424 cites W1969913866 @default.
- W3015108424 cites W1970348378 @default.
- W3015108424 cites W1972084879 @default.
- W3015108424 cites W1972502085 @default.
- W3015108424 cites W1973065567 @default.
- W3015108424 cites W1975160730 @default.
- W3015108424 cites W1975584324 @default.
- W3015108424 cites W1978890358 @default.
- W3015108424 cites W1980431661 @default.
- W3015108424 cites W1981223700 @default.
- W3015108424 cites W1981390911 @default.
- W3015108424 cites W1983171687 @default.
- W3015108424 cites W1984783017 @default.
- W3015108424 cites W1988259047 @default.
- W3015108424 cites W1988835950 @default.
- W3015108424 cites W1991869994 @default.
- W3015108424 cites W1992496831 @default.
- W3015108424 cites W1994246319 @default.
- W3015108424 cites W1998053602 @default.
- W3015108424 cites W1999685593 @default.
- W3015108424 cites W2001188488 @default.
- W3015108424 cites W2001238139 @default.
- W3015108424 cites W2002203539 @default.
- W3015108424 cites W2003782942 @default.
- W3015108424 cites W2004850059 @default.
- W3015108424 cites W2004867175 @default.
- W3015108424 cites W2008245372 @default.
- W3015108424 cites W2011707142 @default.
- W3015108424 cites W2012029570 @default.
- W3015108424 cites W2013760130 @default.
- W3015108424 cites W2016629161 @default.
- W3015108424 cites W2018404393 @default.
- W3015108424 cites W2020270439 @default.
- W3015108424 cites W2021719123 @default.
- W3015108424 cites W2022643689 @default.
- W3015108424 cites W2024346417 @default.
- W3015108424 cites W2026188340 @default.
- W3015108424 cites W2026885884 @default.
- W3015108424 cites W2028440612 @default.
- W3015108424 cites W2029349345 @default.
- W3015108424 cites W2030061457 @default.
- W3015108424 cites W2031183049 @default.
- W3015108424 cites W2031535056 @default.
- W3015108424 cites W2032510498 @default.
- W3015108424 cites W2032689600 @default.
- W3015108424 cites W2035571885 @default.
- W3015108424 cites W2036121419 @default.
- W3015108424 cites W2036260022 @default.
- W3015108424 cites W2037717112 @default.
- W3015108424 cites W2043585725 @default.
- W3015108424 cites W2043935388 @default.
- W3015108424 cites W2046116701 @default.
- W3015108424 cites W2048275987 @default.
- W3015108424 cites W2049071195 @default.
- W3015108424 cites W2049685426 @default.
- W3015108424 cites W2050285438 @default.
- W3015108424 cites W2054810910 @default.
- W3015108424 cites W2063301167 @default.
- W3015108424 cites W2066278849 @default.
- W3015108424 cites W2071865335 @default.
- W3015108424 cites W2073308447 @default.
- W3015108424 cites W2075171546 @default.
- W3015108424 cites W2075668437 @default.
- W3015108424 cites W2076204872 @default.
- W3015108424 cites W2077168880 @default.
- W3015108424 cites W2081472130 @default.
- W3015108424 cites W2081660555 @default.
- W3015108424 cites W2082105021 @default.
- W3015108424 cites W2084276370 @default.
- W3015108424 cites W2088787815 @default.
- W3015108424 cites W2092808790 @default.
- W3015108424 cites W2094422845 @default.
- W3015108424 cites W2094834258 @default.
- W3015108424 cites W2096660674 @default.
- W3015108424 cites W2100389601 @default.
- W3015108424 cites W2102543514 @default.
- W3015108424 cites W2104699219 @default.
- W3015108424 cites W2105532895 @default.
- W3015108424 cites W2108518419 @default.
- W3015108424 cites W2111118274 @default.
- W3015108424 cites W2111896964 @default.