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• W3015236699 abstract "${text{ScPO}}_{4}$ and ${text{YPO}}_{4}$ with the tetragonal zircon-structure were studied at room temperature and pressures up to $ensuremath{sim}50text{ }text{GPa}$. Pressure-induced phase transitions to the sheelite structure occur at 30 GPa for ${text{ScPO}}_{4}$ and 16.3 GPa for ${text{YPO}}_{4}$, respectively. In addition to the scheelite-type high-pressure phase, an intermediate phase with the monoclinic monazite-type structure formed during the phase transition process of ${text{YPO}}_{4}$. The high-pressure phases of ${text{ScPO}}_{4}$ and ${text{YPO}}_{4}$ are not quenchable on pressure release. The pressure dependence of the total energy of the different phases was calculated using density-functional method, and the results confirm the experimentally observed phase relations under pressure. Structural parameters and compressibility of each phase were determined by refinement of the x-ray diffraction patterns. The high-pressure phase of ${text{ScPO}}_{4}$ has a very large bulk modulus [376(8) GPa]." @default.
• W3015236699 created "2020-04-17" @default.
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• W3015236699 date "2009-11-24" @default.
• W3015236699 modified "2023-09-23" @default.
• W3015236699 title "High-pressure phase transitions of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mtext>ScPO</mml:mtext></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math>and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mtext>YPO</mml:mtext></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math>" @default.
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• W3015236699 doi "https://doi.org/10.1103/physrevb.80.184114" @default.
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