FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3015280209> ?p ?o ?g. }

• W3015280209 endingPage "4382" @default.
• W3015280209 startingPage "4370" @default.
• W3015280209 abstract "MXenes are a recently discovered class of two-dimensional materials that have shown great potential as electrodes in electrochemical energy storage devices. Despite their promise in this area, MXenes can still suffer limitations in the form of restricted ion accessibility between the closely spaced multistacked MXene layers causing low capacities and poor cycle life. Pillaring, where a secondary species is inserted between layers, has been used to increase interlayer spacings in clays with great success but has had limited application in MXenes. We report a new amine-assisted pillaring methodology that successfully intercalates silica-based pillars between Ti3C2 layers. Using this technique, the interlayer spacing can be controlled with the choice of amine and calcination temperature, up to a maximum of 3.2 nm, the largest interlayer spacing reported for an MXene. Another effect of the pillaring is a dramatic increase in surface area, achieving BET surface areas of 235 m2 g-1, a sixty-fold increase over the unpillared material and the highest reported for MXenes using an intercalation-based method. The intercalation mechanism was revealed by different characterization techniques, allowing the surface chemistry to be optimized for the pillaring process. The porous MXene was tested for Na-ion battery applications and showed superior capacity, rate capability and remarkable stability compared with those of the nonpillared materials, retaining 98.5% capacity between the 50th and 100th cycles. These results demonstrate the applicability and promise of pillaring techniques applied to MXenes providing a new approach to optimizing their properties for a range of applications, including energy storage, conversion, catalysis, and gas separations." @default.
• W3015280209 created "2020-04-17" @default.
• W3015280209 creator A5000909826 @default.
• W3015280209 creator A5003096975 @default.
• W3015280209 creator A5014184744 @default.
• W3015280209 creator A5018305010 @default.
• W3015280209 creator A5021891067 @default.
• W3015280209 creator A5027740549 @default.
• W3015280209 creator A5032613066 @default.
• W3015280209 creator A5043307269 @default.
• W3015280209 creator A5043824550 @default.
• W3015280209 creator A5080752278 @default.
• W3015280209 creator A5084315860 @default.
• W3015280209 date "2020-04-10" @default.
• W3015280209 modified "2023-10-17" @default.
• W3015280209 title "Porous Silica-Pillared MXenes with Controllable Interlayer Distances for Long-Life Na-Ion Batteries" @default.
• W3015280209 cites W1914863589 @default.
• W3015280209 cites W1936017161 @default.
• W3015280209 cites W1970320842 @default.
• W3015280209 cites W1982027827 @default.
• W3015280209 cites W1982345975 @default.
• W3015280209 cites W1984277410 @default.
• W3015280209 cites W1988080928 @default.
• W3015280209 cites W1993066888 @default.
• W3015280209 cites W1999023472 @default.
• W3015280209 cites W2014451195 @default.
• W3015280209 cites W2025907669 @default.
• W3015280209 cites W2049965679 @default.
• W3015280209 cites W2053424789 @default.
• W3015280209 cites W2068580515 @default.
• W3015280209 cites W2075495298 @default.
• W3015280209 cites W2084927324 @default.
• W3015280209 cites W2085852740 @default.
• W3015280209 cites W2124469076 @default.
• W3015280209 cites W2143467751 @default.
• W3015280209 cites W2155175869 @default.
• W3015280209 cites W2161947509 @default.
• W3015280209 cites W2164255475 @default.
• W3015280209 cites W2199596118 @default.
• W3015280209 cites W2258223240 @default.
• W3015280209 cites W2291109238 @default.
• W3015280209 cites W2299753553 @default.
• W3015280209 cites W2322329436 @default.
• W3015280209 cites W2395797432 @default.
• W3015280209 cites W2418435616 @default.
• W3015280209 cites W2420611669 @default.
• W3015280209 cites W2511239946 @default.
• W3015280209 cites W2554324297 @default.
• W3015280209 cites W2566192085 @default.
• W3015280209 cites W2623547044 @default.
• W3015280209 cites W2755762201 @default.
• W3015280209 cites W2768088004 @default.
• W3015280209 cites W2789441573 @default.
• W3015280209 cites W2793579727 @default.
• W3015280209 cites W2794554745 @default.
• W3015280209 cites W2796776754 @default.
• W3015280209 cites W2800045975 @default.
• W3015280209 cites W2884549976 @default.
• W3015280209 cites W2888447136 @default.
• W3015280209 cites W2893535434 @default.
• W3015280209 cites W2897055776 @default.
• W3015280209 cites W2898318198 @default.
• W3015280209 cites W2899260625 @default.
• W3015280209 cites W2900547507 @default.
• W3015280209 cites W2901816612 @default.
• W3015280209 cites W2902797989 @default.
• W3015280209 cites W2905711458 @default.
• W3015280209 cites W2909548133 @default.
• W3015280209 cites W2937367149 @default.
• W3015280209 cites W2949405579 @default.
• W3015280209 cites W2949449262 @default.
• W3015280209 cites W3012389106 @default.
• W3015280209 cites W843007777 @default.
• W3015280209 doi "https://doi.org/10.1021/acs.langmuir.0c00462" @default.
• W3015280209 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7581309" @default.
• W3015280209 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32275436" @default.
• W3015280209 hasPublicationYear "2020" @default.
• W3015280209 type Work @default.
• W3015280209 sameAs 3015280209 @default.
• W3015280209 citedByCount "26" @default.
• W3015280209 countsByYear W30152802092020 @default.
• W3015280209 countsByYear W30152802092021 @default.
• W3015280209 countsByYear W30152802092022 @default.
• W3015280209 countsByYear W30152802092023 @default.
• W3015280209 crossrefType "journal-article" @default.
• W3015280209 hasAuthorship W3015280209A5000909826 @default.
• W3015280209 hasAuthorship W3015280209A5003096975 @default.
• W3015280209 hasAuthorship W3015280209A5014184744 @default.
• W3015280209 hasAuthorship W3015280209A5018305010 @default.
• W3015280209 hasAuthorship W3015280209A5021891067 @default.
• W3015280209 hasAuthorship W3015280209A5027740549 @default.
• W3015280209 hasAuthorship W3015280209A5032613066 @default.
• W3015280209 hasAuthorship W3015280209A5043307269 @default.
• W3015280209 hasAuthorship W3015280209A5043824550 @default.
• W3015280209 hasAuthorship W3015280209A5080752278 @default.
• W3015280209 hasAuthorship W3015280209A5084315860 @default.
• W3015280209 hasBestOaLocation W30152802091 @default.
• W3015280209 hasConcept C121332964 @default.

• next