FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3015280490> ?p ?o ?g. }

• W3015280490 endingPage "5229" @default.
• W3015280490 startingPage "5223" @default.
• W3015280490 abstract "Coordination polymerization of 1-phenyl-1,3-butadiene (1PB) has been carried out using diiminophosphinato lutetium complexes 1 and 2, pyridyl-methylene-fluorenyl complexes 3 (Sc 3a; Lu 3b; Y 3c) and 4 (Sc 4a; Lu 4b; Y 4c), β-diketiminato yttrium complex 5, bis(imino)aryl gadolinium complex 6, bis(phosphino)carbazolide yttrium complex 7, and bis(phosphinophenyl)amido yttrium complex 8. Complexes 1, 2, 3a,b, and 4a,b, under the activation of [Ph3C][B(C6F5)4] and AliBu3, show high activities as well as higher than 96.6% 3,4-regioselectivities, of which 1 and 2 are nonstereoselective, giving atactic 3,4-poly(1PB), while 3a,b and 4a,b exhibit distinguished syndioselectivities (≥95.3% rrrr). However, 3c and 4c are inactive. In addition, complexes 5–7 are also completely inert although they are highly active and cis-1,4-selective for isoprene polymerization. On the contrary, the analogous cis-1,4-selective complex 8 exhibits syndio- (≥96.1% rrrr) and 3,4-regio- (>99%) selectivity. Hydrogenation of a syndiotactic 3,4-poly(1PB) affords a syndiotactic poly(4-phenyl-1-butene) elastomer with a Tg of 17 °C. The cationic cyclization transfers a syndiotactic 3,4-poly(1PB) into a rigid cyclized polyolefin with a Tg as high as 327 °C. Density functional theory (DFT) simulations are employed to illustrate the mechanisms for the control of activity and stereoselectivity from thermodynamic and geometric viewpoints." @default.
• W3015280490 created "2020-04-17" @default.
• W3015280490 creator A5047110002 @default.
• W3015280490 creator A5054519421 @default.
• W3015280490 creator A5054994208 @default.
• W3015280490 creator A5072434494 @default.
• W3015280490 creator A5074389310 @default.
• W3015280490 date "2020-04-08" @default.
• W3015280490 modified "2023-10-15" @default.
• W3015280490 title "Syndioselective 3,4-Polymerization of 1-Phenyl-1,3-Butadiene by Rare-Earth Metal Catalysts" @default.
• W3015280490 cites W1654083484 @default.
• W3015280490 cites W1966149855 @default.
• W3015280490 cites W1966839330 @default.
• W3015280490 cites W1987982541 @default.
• W3015280490 cites W2006383694 @default.
• W3015280490 cites W2021389295 @default.
• W3015280490 cites W2022489062 @default.
• W3015280490 cites W2029579581 @default.
• W3015280490 cites W2031158880 @default.
• W3015280490 cites W2031438052 @default.
• W3015280490 cites W2034606880 @default.
• W3015280490 cites W2048611587 @default.
• W3015280490 cites W2055662875 @default.
• W3015280490 cites W2082973001 @default.
• W3015280490 cites W2092951467 @default.
• W3015280490 cites W2145065557 @default.
• W3015280490 cites W2160923526 @default.
• W3015280490 cites W2273888849 @default.
• W3015280490 cites W2317364598 @default.
• W3015280490 cites W2327070249 @default.
• W3015280490 cites W2329363308 @default.
• W3015280490 cites W2332117052 @default.
• W3015280490 cites W2332789863 @default.
• W3015280490 cites W2333448090 @default.
• W3015280490 cites W2418701396 @default.
• W3015280490 cites W2510334707 @default.
• W3015280490 cites W2750109640 @default.
• W3015280490 cites W2908647239 @default.
• W3015280490 cites W2916968331 @default.
• W3015280490 cites W4229540604 @default.
• W3015280490 doi "https://doi.org/10.1021/acscatal.9b04590" @default.
• W3015280490 hasPublicationYear "2020" @default.
• W3015280490 type Work @default.
• W3015280490 sameAs 3015280490 @default.
• W3015280490 citedByCount "12" @default.
• W3015280490 countsByYear W30152804902021 @default.
• W3015280490 countsByYear W30152804902022 @default.
• W3015280490 countsByYear W30152804902023 @default.
• W3015280490 crossrefType "journal-article" @default.
• W3015280490 hasAuthorship W3015280490A5047110002 @default.
• W3015280490 hasAuthorship W3015280490A5054519421 @default.
• W3015280490 hasAuthorship W3015280490A5054994208 @default.
• W3015280490 hasAuthorship W3015280490A5072434494 @default.
• W3015280490 hasAuthorship W3015280490A5074389310 @default.
• W3015280490 hasConcept C155647269 @default.
• W3015280490 hasConcept C161790260 @default.
• W3015280490 hasConcept C178790620 @default.
• W3015280490 hasConcept C183882617 @default.
• W3015280490 hasConcept C185592680 @default.
• W3015280490 hasConcept C188027245 @default.
• W3015280490 hasConcept C2779588249 @default.
• W3015280490 hasConcept C2779851234 @default.
• W3015280490 hasConcept C44228677 @default.
• W3015280490 hasConcept C520551903 @default.
• W3015280490 hasConcept C521977710 @default.
• W3015280490 hasConcept C531131001 @default.
• W3015280490 hasConcept C91819851 @default.
• W3015280490 hasConceptScore W3015280490C155647269 @default.
• W3015280490 hasConceptScore W3015280490C161790260 @default.
• W3015280490 hasConceptScore W3015280490C178790620 @default.
• W3015280490 hasConceptScore W3015280490C183882617 @default.
• W3015280490 hasConceptScore W3015280490C185592680 @default.
• W3015280490 hasConceptScore W3015280490C188027245 @default.
• W3015280490 hasConceptScore W3015280490C2779588249 @default.
• W3015280490 hasConceptScore W3015280490C2779851234 @default.
• W3015280490 hasConceptScore W3015280490C44228677 @default.
• W3015280490 hasConceptScore W3015280490C520551903 @default.
• W3015280490 hasConceptScore W3015280490C521977710 @default.
• W3015280490 hasConceptScore W3015280490C531131001 @default.
• W3015280490 hasConceptScore W3015280490C91819851 @default.
• W3015280490 hasFunder F4320321001 @default.
• W3015280490 hasFunder F4320327282 @default.
• W3015280490 hasIssue "9" @default.
• W3015280490 hasLocation W30152804901 @default.
• W3015280490 hasOpenAccess W3015280490 @default.
• W3015280490 hasPrimaryLocation W30152804901 @default.
• W3015280490 hasRelatedWork W1968682982 @default.
• W3015280490 hasRelatedWork W1992568123 @default.
• W3015280490 hasRelatedWork W2011878589 @default.
• W3015280490 hasRelatedWork W2044521706 @default.
• W3015280490 hasRelatedWork W2076161197 @default.
• W3015280490 hasRelatedWork W2143006470 @default.
• W3015280490 hasRelatedWork W2351654534 @default.
• W3015280490 hasRelatedWork W2633706016 @default.
• W3015280490 hasRelatedWork W3010981130 @default.
• W3015280490 hasRelatedWork W4246154777 @default.
• W3015280490 hasVolume "10" @default.
• W3015280490 isParatext "false" @default.

• next