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- W3015280630 endingPage "297" @default.
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- W3015280630 abstract "Results of dielectric studies in the nematic and isotropic liquid phases of pentylcyanobiphenyl (5CB), a model rod-like liquid crystalline material, are shown. They are based on the discussion of the evolution of dielectric constant ( ε ), its changes under the strong electric field (nonlinear dielectric effect, NDE), and finally, the primary relaxation time. It is shown that changes in ε T and NDE are entirely dominated by the impact of pretransitional fluctuations (pre-nematic and pre-isotropic, respectively) which are associated with the weakly discontinuous character of the isotropic–nematic phase transition. This influence also extends for the low-frequency, ionic species dominated, region. Notable, that the derivative-based and distortions sensitive analysis revealed the tricritical nature of the I-N transition. Although the glass transition in 5CB occurs in the deeply supercooled state at T g ≈ − 68 ° C , the dynamics (changes of the primary relaxation time) follow a previtreous pattern both in the isotropic and in the nematic phase. Finally, the discussion of the ’molecular’ vs. ‘quasi-critical’ characterizations of the isotropic and nematic phases is presented. It shows the evident prevalence of the ‘quasi-critical-picture’, which offers the consistent temperature parameterization in the total tested temperature range." @default.
- W3015280630 created "2020-04-17" @default.
- W3015280630 creator A5043587562 @default.
- W3015280630 date "2020-04-13" @default.
- W3015280630 modified "2023-09-27" @default.
- W3015280630 title "‘Quasi-Tricritical’ and Glassy Dielectric Properties of a Nematic Liquid Crystalline Material" @default.
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- W3015280630 doi "https://doi.org/10.3390/cryst10040297" @default.
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