FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3015290310> ?p ?o ?g. }

• W3015290310 endingPage "6350" @default.
• W3015290310 startingPage "6338" @default.
• W3015290310 abstract "Despite continuing and burgeoning interest in americium (Am) coordination chemistry in recent years, investigations of the electronic structures and bonding chemistry of high oxidation state americium complexes and their implications for minor actinide separation remain relatively less explored to date. Here, we used density functional theory (DFT) to create high oxidation states of americium but experimentally feasible models of Am(V) and Am(VI) complexes of phenanthroline ligand (DAPhen) as [AmO2(L)]1+/2+ and [AmO3(L)]1+ (L = 2,9-bis[(N,N-dimethyl)-carbonyl]-1,10-phenanthroline (oxo-DAPhen, LO) and 2,9-bis[(N,N-dimethyl)-thio-carbonyl]-1,10-phenanthroline (thio-DAPhen, LS)), meanwhile comparing these with [UO2(L)]2+. On the basis of the calculations, the Am(V) and Am(VI) oxidation state are thermodynamically feasible and can be stabilized by DAPhen ligands. From a comparative study, the strength of thio-DAPhen in the separation of high oxidation state Am emerges better than does oxo-DAPhen, which relates to the nature, energy level, and spatial arrangement of their frontier orbitals. This study provides fundamental knowledge toward understanding the transuranic separations processes, which has implications in designing new, more selective extraction processes for the separation of Am from curium (Cm) as well as lanthanide." @default.
• W3015290310 created "2020-04-17" @default.
• W3015290310 creator A5012086743 @default.
• W3015290310 creator A5029360035 @default.
• W3015290310 creator A5034815930 @default.
• W3015290310 creator A5067617117 @default.
• W3015290310 creator A5089406337 @default.
• W3015290310 date "2020-04-14" @default.
• W3015290310 modified "2023-10-17" @default.
• W3015290310 title "Theoretical Insight into Coordination Chemistry of Am(VI) and Am(V) with Phenanthroline Ligand: Implications for High Oxidation State Based Minor Actinide Separation" @default.
• W3015290310 cites W1650728208 @default.
• W3015290310 cites W1891387428 @default.
• W3015290310 cites W1968899402 @default.
• W3015290310 cites W1974931722 @default.
• W3015290310 cites W1976487148 @default.
• W3015290310 cites W1981448282 @default.
• W3015290310 cites W1989640278 @default.
• W3015290310 cites W2000380304 @default.
• W3015290310 cites W2003203136 @default.
• W3015290310 cites W2006786785 @default.
• W3015290310 cites W2014660603 @default.
• W3015290310 cites W2023390323 @default.
• W3015290310 cites W2028747545 @default.
• W3015290310 cites W2043057467 @default.
• W3015290310 cites W2055563809 @default.
• W3015290310 cites W2060955206 @default.
• W3015290310 cites W2068049269 @default.
• W3015290310 cites W2072059432 @default.
• W3015290310 cites W2073322341 @default.
• W3015290310 cites W2074254520 @default.
• W3015290310 cites W2079576114 @default.
• W3015290310 cites W2084472127 @default.
• W3015290310 cites W2088177183 @default.
• W3015290310 cites W2090056623 @default.
• W3015290310 cites W2093211330 @default.
• W3015290310 cites W2096747776 @default.
• W3015290310 cites W2100107857 @default.
• W3015290310 cites W2107668628 @default.
• W3015290310 cites W2109364787 @default.
• W3015290310 cites W2110406282 @default.
• W3015290310 cites W2116373706 @default.
• W3015290310 cites W2122134641 @default.
• W3015290310 cites W2150345533 @default.
• W3015290310 cites W2159253311 @default.
• W3015290310 cites W2160923526 @default.
• W3015290310 cites W2166739348 @default.
• W3015290310 cites W2168542043 @default.
• W3015290310 cites W2212253603 @default.
• W3015290310 cites W2317012604 @default.
• W3015290310 cites W2317712071 @default.
• W3015290310 cites W2318714981 @default.
• W3015290310 cites W2330250271 @default.
• W3015290310 cites W2335170026 @default.
• W3015290310 cites W2338069988 @default.
• W3015290310 cites W2410924018 @default.
• W3015290310 cites W2608653422 @default.
• W3015290310 cites W2746336898 @default.
• W3015290310 cites W2754286365 @default.
• W3015290310 cites W2788334169 @default.
• W3015290310 cites W2790157302 @default.
• W3015290310 cites W2949490524 @default.
• W3015290310 cites W2949763367 @default.
• W3015290310 cites W2950053519 @default.
• W3015290310 cites W3005002842 @default.
• W3015290310 cites W4255389013 @default.
• W3015290310 doi "https://doi.org/10.1021/acs.inorgchem.0c00452" @default.
• W3015290310 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32286060" @default.
• W3015290310 hasPublicationYear "2020" @default.
• W3015290310 type Work @default.
• W3015290310 sameAs 3015290310 @default.
• W3015290310 citedByCount "19" @default.
• W3015290310 countsByYear W30152903102020 @default.
• W3015290310 countsByYear W30152903102021 @default.
• W3015290310 countsByYear W30152903102022 @default.
• W3015290310 countsByYear W30152903102023 @default.
• W3015290310 crossrefType "journal-article" @default.
• W3015290310 hasAuthorship W3015290310A5012086743 @default.
• W3015290310 hasAuthorship W3015290310A5029360035 @default.
• W3015290310 hasAuthorship W3015290310A5034815930 @default.
• W3015290310 hasAuthorship W3015290310A5067617117 @default.
• W3015290310 hasAuthorship W3015290310A5089406337 @default.
• W3015290310 hasConcept C116569031 @default.
• W3015290310 hasConcept C135788738 @default.
• W3015290310 hasConcept C145148216 @default.
• W3015290310 hasConcept C147597530 @default.
• W3015290310 hasConcept C152365726 @default.
• W3015290310 hasConcept C161790260 @default.
• W3015290310 hasConcept C170493617 @default.
• W3015290310 hasConcept C178790620 @default.
• W3015290310 hasConcept C179104552 @default.
• W3015290310 hasConcept C185592680 @default.
• W3015290310 hasConcept C201770740 @default.
• W3015290310 hasConcept C2777660389 @default.
• W3015290310 hasConcept C2778591166 @default.
• W3015290310 hasConcept C2781253882 @default.
• W3015290310 hasConcept C544153396 @default.
• W3015290310 hasConcept C552554468 @default.
• W3015290310 hasConcept C55493867 @default.

• next