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• W3015679119 endingPage "1782" @default.
• W3015679119 startingPage "1775" @default.
• W3015679119 abstract "This article describes the synthesis and full photophysical studies at room and low temperature of a series of iridium(III) complexes incorporating an ethynyl‐extended benzoxazole‐based ancillary ligand. The electronic nature of the terminal end‐group of the ancillary ligand was modulated by the simple introduction of electron‐donating (Me, NBu 2 ) or ‐withdrawing (CN) groups. For all complexes, TD‐DFT calculations showed that the lowest‐lying transition was ligand‐centered and that the nature of the first triplet state was very sensitive to electronic parameters leading to a charge transfer (CT) or locally excited (LE) excited state, always centered on the ancillary ligand. Singlet oxygen sensitization studies were performed on all compounds, showing that iridium(III) complexes containing cyano‐functionalized ligands feature sensitization parameters, making them attractive candidates for photodynamic therapy." @default.
• W3015679119 created "2020-04-17" @default.
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• W3015679119 date "2020-04-29" @default.
• W3015679119 modified "2023-10-14" @default.
• W3015679119 title "Phosphorescent Cyclometalated Iridium(III) Complexes Bearing Ethynyl-Extended 2-(2'-Hydroxyphenyl) Benzoxazole Ancillary Ligands" @default.
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• W3015679119 doi "https://doi.org/10.1002/ejic.202000114" @default.
• W3015679119 hasPublicationYear "2020" @default.
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