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- W3016124967 abstract "It’s dinnertime, and the only food in your house is a can of beans and a box of spaghetti. What can you make? A new mapping method that combines known reactants in unfamiliar ways can help organic chemists solve a similar problem. Instead of reacting an amine and a carboxylic acid in the usual amide-coupling reaction, Tim Cernak and coworkers at the University of Michigan found that chemists can combine these compounds in 320 ways (Nature 2020, DOI: 10.1038/s41586-020-2142-y). The team created a mathematical model by taking all the possible combinations of an amine and a carboxylic acid and using their equation to find a number of potential products. For example, the two starting materials can couple to form the amide, but they can also go through a decarboxylation to form an amine, or a tandem decarboxylation-deamination to give a new C–C bond (shown). Using their system, the team found" @default.
- W3016124967 created "2020-04-17" @default.
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- W3016124967 date "2020-04-06" @default.
- W3016124967 modified "2023-09-27" @default.
- W3016124967 title "Mapping the chemical reaction space" @default.
- W3016124967 doi "https://doi.org/10.1021/cen-09813-scicon1" @default.
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