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- W3016163658 abstract "A Brönsted acid multicomponent reaction between pyruvate derivatives, amines, and aldehydes for the preparation of phosphorus and fluorine substituted γ-lactam derivatives is presented. Depending on the substitution in the resulting 1,5-dihydro-2H-pyrrol-2-one substrates, the reaction provides enol- or enamine-derived γ-lactams. Some enantioselective examples of this reaction are also reported using chiral phosphoric acids as organocatalysts. Moreover, several synthetic applications of γ-lactam derivatives are presented including some examples of highly diastereoselective transformations." @default.
- W3016163658 created "2020-04-17" @default.
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- W3016163658 date "2020-04-15" @default.
- W3016163658 modified "2023-10-10" @default.
- W3016163658 title "Brönsted Acid Catalyzed Multicomponent Synthesis of Phosphorus and Fluorine-Derived γ-Lactam Derivatives" @default.
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- W3016163658 doi "https://doi.org/10.1021/acs.joc.0c00280" @default.
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