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- W3016566235 abstract "Here we present the design and synthesis of a new robust microporous organic polymer (TPBP) decorated with phenazine groups which endowed reversibly redox-active properties. The obtained TPBP possesses relatively high surface area (359 m2/g) and good thermal stability. TPBP exhibits excellent catalytic capability for the oxidative homocoupling of amines with high activity and selectivity toward target products. Besides, this metal-free catalyst demonstrated excellent recyclability after 6 cycles under the investigated conditions. By means of EPR and UV-vis spectroscopy, a plausible mechanism of the amine oxidative coupling reaction was deduced via a single electron transfer from TPBP radical cations to amine substrates." @default.
- W3016566235 created "2020-04-24" @default.
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- W3016566235 date "2020-05-01" @default.
- W3016566235 modified "2023-09-27" @default.
- W3016566235 title "A robust phenazine-containing organic polymer as catalyst for amine oxidative coupling reactions" @default.
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- W3016566235 doi "https://doi.org/10.1016/j.jcat.2020.03.031" @default.
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