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- W3016844740 abstract "The pressure-induced structural phase transitions of e- and γ-CL-20 were studied by Raman and mid-infrared spectroscopy up to 60 GPa. In this work, the phase transition of CL-20 from the e-phase to the γ′-phase starts at 0.9 GPa and ends at 4.4 GPa. The γ′-phase in this work is distinctly different from the γ-phase recognized by the energetic community in terms of the structure and properties. Subsequently, the η phase starts at 6.9 GPa and ends at 10.6 GPa because of the slight cage distortion. With further increase of the loading pressure, two new phases, φ and ι, were observed at 28 and 50 GPa, respectively. The infrared results are consistent with Raman results and show that similar phase regions are observed for CL-20 under high pressures. The behavior of the γ-phase under pressure indicates that the ζ-phase appears at 1.3 GPa and sustains its stability up to 47.4 GPa. The current results prove that the newly discovered γ′-phase is evidently distinct from the γ-phase and they undergo different phase transition routes under loading compression." @default.
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- W3016844740 date "2020-01-01" @default.
- W3016844740 modified "2023-09-23" @default.
- W3016844740 title "Phase Transition Routes for ε- and γ-CL-20 Crystals under High Pressures of up to 60 GPa" @default.
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