Matches in SemOpenAlex for { <https://semopenalex.org/work/W3016976384> ?p ?o ?g. }
- W3016976384 endingPage "7503" @default.
- W3016976384 startingPage "7487" @default.
- W3016976384 abstract "The octaphosphine {cyclo-(P4tBu3)}2 (1) possesses a multifaceted coordination chemistry. The predominant binding mode is a P,P-chelate, e.g., in the monometallic chelate complex [MLL′(1-κ2P2,P4′)] in which the ligand 1 adopts a gauche conformation. Examples include square-planar (M = RhI, L = CO, L′ = Cl (2), M = PdII, L = L′ = Cl (3), M = PtII, L = L′ = Cl (9)), tetrahedral (M = Co–I, L = NO, L′ = CO (4)), and trigonal-planar complexes [ML(1-κ2P2,P4′)] (M = Pd0, L = PPh3, (5), M = CuI, L = Br (6)). With 2 equiv of [CuBr(SMe2)], a dinuclear complex [(CuBr)2(1-κ2P2,P2′,κ2P4,P4′)] (7) was obtained which features a synperiplanar conformation of the octaphosphine. A second coordination mode was also observed in [PtCl2(1-κ2P1,P2′)] (10) in which the bridge phosphorus atom in octaphosphine 1 is involved in the chelation, with the ligand in an antiperiplanar conformation. Thermolysis of selected complexes showed them to be suitable candidates for the generation of phosphorus-rich metal phosphides MPx (x > 1)." @default.
- W3016976384 created "2020-04-24" @default.
- W3016976384 creator A5011359523 @default.
- W3016976384 creator A5059219605 @default.
- W3016976384 date "2020-04-21" @default.
- W3016976384 modified "2023-09-30" @default.
- W3016976384 title "Versatile Coordination Chemistry of Hexa-<i>tert</i>-butyl-octaphosphine" @default.
- W3016976384 cites W1493717129 @default.
- W3016976384 cites W1512801761 @default.
- W3016976384 cites W1524238293 @default.
- W3016976384 cites W1608918330 @default.
- W3016976384 cites W1964682855 @default.
- W3016976384 cites W1965637090 @default.
- W3016976384 cites W1977076528 @default.
- W3016976384 cites W1979945615 @default.
- W3016976384 cites W1980563556 @default.
- W3016976384 cites W1981471366 @default.
- W3016976384 cites W1984251321 @default.
- W3016976384 cites W1985326074 @default.
- W3016976384 cites W1985644977 @default.
- W3016976384 cites W1987001065 @default.
- W3016976384 cites W1988091937 @default.
- W3016976384 cites W1990170643 @default.
- W3016976384 cites W1990578023 @default.
- W3016976384 cites W2007209007 @default.
- W3016976384 cites W2012866556 @default.
- W3016976384 cites W2015946675 @default.
- W3016976384 cites W2021477372 @default.
- W3016976384 cites W2022663243 @default.
- W3016976384 cites W2022704398 @default.
- W3016976384 cites W2027440879 @default.
- W3016976384 cites W2032654940 @default.
- W3016976384 cites W2037579052 @default.
- W3016976384 cites W2043060584 @default.
- W3016976384 cites W2047262901 @default.
- W3016976384 cites W2049432770 @default.
- W3016976384 cites W2049773939 @default.
- W3016976384 cites W2050384421 @default.
- W3016976384 cites W2052107636 @default.
- W3016976384 cites W2052884636 @default.
- W3016976384 cites W2058210956 @default.
- W3016976384 cites W2060075968 @default.
- W3016976384 cites W2060897759 @default.
- W3016976384 cites W2061617600 @default.
- W3016976384 cites W2063239390 @default.
- W3016976384 cites W2064068872 @default.
- W3016976384 cites W2065811073 @default.
- W3016976384 cites W2067718414 @default.
- W3016976384 cites W2070884466 @default.
- W3016976384 cites W2073945973 @default.
- W3016976384 cites W2078146328 @default.
- W3016976384 cites W2084185706 @default.
- W3016976384 cites W2087232030 @default.
- W3016976384 cites W2092157292 @default.
- W3016976384 cites W2093015890 @default.
- W3016976384 cites W2096747776 @default.
- W3016976384 cites W2105189720 @default.
- W3016976384 cites W2128333990 @default.
- W3016976384 cites W2132454074 @default.
- W3016976384 cites W2140334553 @default.
- W3016976384 cites W2144151019 @default.
- W3016976384 cites W2148284063 @default.
- W3016976384 cites W2150195378 @default.
- W3016976384 cites W2156257115 @default.
- W3016976384 cites W2169508484 @default.
- W3016976384 cites W2510400859 @default.
- W3016976384 cites W2592712930 @default.
- W3016976384 cites W2593304310 @default.
- W3016976384 cites W2763195457 @default.
- W3016976384 cites W2911008714 @default.
- W3016976384 cites W2949751302 @default.
- W3016976384 cites W2991047625 @default.
- W3016976384 cites W2999099796 @default.
- W3016976384 cites W3004936839 @default.
- W3016976384 cites W3005166743 @default.
- W3016976384 cites W4254752969 @default.
- W3016976384 doi "https://doi.org/10.1021/acs.inorgchem.0c00262" @default.
- W3016976384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32314912" @default.
- W3016976384 hasPublicationYear "2020" @default.
- W3016976384 type Work @default.
- W3016976384 sameAs 3016976384 @default.
- W3016976384 citedByCount "7" @default.
- W3016976384 countsByYear W30169763842021 @default.
- W3016976384 countsByYear W30169763842022 @default.
- W3016976384 countsByYear W30169763842023 @default.
- W3016976384 crossrefType "journal-article" @default.
- W3016976384 hasAuthorship W3016976384A5011359523 @default.
- W3016976384 hasAuthorship W3016976384A5059219605 @default.
- W3016976384 hasBestOaLocation W30169763842 @default.
- W3016976384 hasConcept C115624301 @default.
- W3016976384 hasConcept C116569031 @default.
- W3016976384 hasConcept C155518411 @default.
- W3016976384 hasConcept C155647269 @default.
- W3016976384 hasConcept C160434732 @default.
- W3016976384 hasConcept C170493617 @default.
- W3016976384 hasConcept C178790620 @default.
- W3016976384 hasConcept C179104552 @default.
- W3016976384 hasConcept C185592680 @default.