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- W3017168934 abstract "Two coplanar tetranuclear Ln(III) clusters, [Ln4(acac)4(μ2-L)6(μ3-OH)2]·2C2H5OH (Ln = Tb (1) and Dy (2)) constructed by one Schiff base ligand (HL = 5-((4-methylbenzylidene)amino)quinolin-8-ol) and a β-diketonate ligand (Hacac = acetylacetone), have been synthesized and structurally and magnetically characterized. Alternating-current (ac) susceptibility measurements reveal that no significant out-of-phase (χ″) ac signals were observed in 1, however, the remarkable slow magnetic relaxation behavior were occurred for 2 with the anisotropic barrier (ΔE/kB) of 82.1 K and τ0 of 6.34 × 10−8 s. Interestingly, two maxima out-of-phase (χ″) ac signals are appeared in 2, which are indicative of the operation of more than one relaxation process. In addition, the luminescence properties of clusters 1 and 2 were studied." @default.
- W3017168934 created "2020-04-24" @default.
- W3017168934 creator A5033732336 @default.
- W3017168934 creator A5075306346 @default.
- W3017168934 date "2020-09-01" @default.
- W3017168934 modified "2023-09-26" @default.
- W3017168934 title "Structures, fluorescent properties and single-molecule-magnet behavior of two Ln4 (LnIII = Tb and Dy) clusters" @default.
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- W3017168934 doi "https://doi.org/10.1016/j.molstruc.2020.128241" @default.
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