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- W3017223887 endingPage "109521" @default.
- W3017223887 startingPage "109521" @default.
- W3017223887 abstract "The high-level ammonium-nitrogen (NH 4 + -N) is a contaminant for aqueous environment but a potential hydrogen fuel . This study investigated an approach of increasing ammonia recovery via adding sodium sulfate of 0–1.5 M to prevent from nitrogen generation. The results of experiment tests, electrochemical analysis and MD simulation demonstrated that the added Na 2 SO 4 assisted ammonium transport inhibited nitrogen gas generation in a certain concentration range. In electric double layer (EDL), with Na 2 SO 4 concentration increasing, both the migration velocities of NH 4 + and Na + are accelerated for Na 2 SO 4 of 0–0.25 M, whereas they are decelerated for concentrate Na 2 SO 4 that 0.5 M). A thick layer formed by Na + that imposed a fierce competitive adsorption blocked the migration of NH 4 + and the transportation of electrons. The decrease of electrons and the accumulation of water molecules caused the potential drop in the EDL. 0.25 M Na 2 SO 4 was the optimal concentration from the aspect of ion transports. The results obtained in this study can allow the manipulation of EDI capacity optimization. • Na + competitively affects NH 4 + migration. • Increasing Na 2 SO 4 concentration weakens NH 4 + reduction. • Na + absorption competitively reduces NH 4 + concentration. • Na–H 2 O ion atmosphere impedes NH 4 + closing to EDL." @default.
- W3017223887 created "2020-04-24" @default.
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- W3017223887 date "2020-07-01" @default.
- W3017223887 modified "2023-09-23" @default.
- W3017223887 title "Increasing ammonia recovery from high-level ammonium wastewater via adding sodium sulfate to prevent nitrogen generation in the cathode" @default.
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- W3017223887 doi "https://doi.org/10.1016/j.envres.2020.109521" @default.
- W3017223887 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32335429" @default.
- W3017223887 hasPublicationYear "2020" @default.
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