Matches in SemOpenAlex for { <https://semopenalex.org/work/W3017625823> ?p ?o ?g. }
- W3017625823 endingPage "121612" @default.
- W3017625823 startingPage "121612" @default.
- W3017625823 abstract "Binding of functionalized organic molecules to oxide surfaces is an important step in the rational design of molecular devices. In the present investigation, we used synchrotron radiation photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy to determine the binding mode, electronic structure and adsorption geometry of phenylphosphonic acid (PPA) on TiO2(110)–(1 × 1). We found that PPA multilayers desorb below 380 K leaving a compact PPA monolayer adsorbed on the surface, which remains stable up to 780 K. In the 380–520 K temperature range, molecules are anchored to the surface via a single P–O–Ti covalent bond (monodentate configuration). Furthermore, the phenyl ring is tilted ~45° with respect to the surface plane and it either forms 45° or is randomly oriented with respect to [001] crystallographic direction. Raising the temperature above 520 K partially transforms the monodentate configuration to a mixed one- and twofold deprotonated bidentate binding mode, presumably after surface hydroxyl groups leave the surface as water molecules. This change in molecular binding does not alter the molecular electronic structure nor the adsorption geometry, which remain essentially unchanged." @default.
- W3017625823 created "2020-05-01" @default.
- W3017625823 creator A5016530565 @default.
- W3017625823 creator A5028683158 @default.
- W3017625823 creator A5035111702 @default.
- W3017625823 creator A5052230196 @default.
- W3017625823 creator A5052268830 @default.
- W3017625823 creator A5075780358 @default.
- W3017625823 creator A5082526034 @default.
- W3017625823 creator A5082918470 @default.
- W3017625823 date "2020-08-01" @default.
- W3017625823 modified "2023-10-17" @default.
- W3017625823 title "Adsorption of phenylphosphonic acid on rutile TiO2(110)" @default.
- W3017625823 cites W1963491130 @default.
- W3017625823 cites W1968394445 @default.
- W3017625823 cites W1970111667 @default.
- W3017625823 cites W1978636393 @default.
- W3017625823 cites W1980216394 @default.
- W3017625823 cites W1986252415 @default.
- W3017625823 cites W1986879571 @default.
- W3017625823 cites W1987478108 @default.
- W3017625823 cites W1994131884 @default.
- W3017625823 cites W1994984182 @default.
- W3017625823 cites W2002803038 @default.
- W3017625823 cites W2016739894 @default.
- W3017625823 cites W2017462961 @default.
- W3017625823 cites W2019886160 @default.
- W3017625823 cites W2022486011 @default.
- W3017625823 cites W2032351859 @default.
- W3017625823 cites W2036360792 @default.
- W3017625823 cites W2061066881 @default.
- W3017625823 cites W2061308021 @default.
- W3017625823 cites W2062083501 @default.
- W3017625823 cites W2071534880 @default.
- W3017625823 cites W2072677085 @default.
- W3017625823 cites W2072696040 @default.
- W3017625823 cites W2077062110 @default.
- W3017625823 cites W2082188792 @default.
- W3017625823 cites W2091684628 @default.
- W3017625823 cites W2093348224 @default.
- W3017625823 cites W2116327492 @default.
- W3017625823 cites W2294810960 @default.
- W3017625823 cites W2327974676 @default.
- W3017625823 cites W2520914000 @default.
- W3017625823 cites W2620809324 @default.
- W3017625823 cites W2623238982 @default.
- W3017625823 cites W2939251952 @default.
- W3017625823 cites W2954498386 @default.
- W3017625823 cites W4292053748 @default.
- W3017625823 doi "https://doi.org/10.1016/j.susc.2020.121612" @default.
- W3017625823 hasPublicationYear "2020" @default.
- W3017625823 type Work @default.
- W3017625823 sameAs 3017625823 @default.
- W3017625823 citedByCount "6" @default.
- W3017625823 countsByYear W30176258232021 @default.
- W3017625823 countsByYear W30176258232022 @default.
- W3017625823 countsByYear W30176258232023 @default.
- W3017625823 crossrefType "journal-article" @default.
- W3017625823 hasAuthorship W3017625823A5016530565 @default.
- W3017625823 hasAuthorship W3017625823A5028683158 @default.
- W3017625823 hasAuthorship W3017625823A5035111702 @default.
- W3017625823 hasAuthorship W3017625823A5052230196 @default.
- W3017625823 hasAuthorship W3017625823A5052268830 @default.
- W3017625823 hasAuthorship W3017625823A5075780358 @default.
- W3017625823 hasAuthorship W3017625823A5082526034 @default.
- W3017625823 hasAuthorship W3017625823A5082918470 @default.
- W3017625823 hasConcept C115624301 @default.
- W3017625823 hasConcept C118629725 @default.
- W3017625823 hasConcept C121332964 @default.
- W3017625823 hasConcept C145148216 @default.
- W3017625823 hasConcept C147597530 @default.
- W3017625823 hasConcept C147789679 @default.
- W3017625823 hasConcept C150394285 @default.
- W3017625823 hasConcept C162711632 @default.
- W3017625823 hasConcept C175708663 @default.
- W3017625823 hasConcept C178516000 @default.
- W3017625823 hasConcept C178790620 @default.
- W3017625823 hasConcept C184779094 @default.
- W3017625823 hasConcept C185592680 @default.
- W3017625823 hasConcept C2777889555 @default.
- W3017625823 hasConcept C32909587 @default.
- W3017625823 hasConcept C46141821 @default.
- W3017625823 hasConcept C55493867 @default.
- W3017625823 hasConcept C7070889 @default.
- W3017625823 hasConcept C8010536 @default.
- W3017625823 hasConcept C86025842 @default.
- W3017625823 hasConcept C93282013 @default.
- W3017625823 hasConceptScore W3017625823C115624301 @default.
- W3017625823 hasConceptScore W3017625823C118629725 @default.
- W3017625823 hasConceptScore W3017625823C121332964 @default.
- W3017625823 hasConceptScore W3017625823C145148216 @default.
- W3017625823 hasConceptScore W3017625823C147597530 @default.
- W3017625823 hasConceptScore W3017625823C147789679 @default.
- W3017625823 hasConceptScore W3017625823C150394285 @default.
- W3017625823 hasConceptScore W3017625823C162711632 @default.
- W3017625823 hasConceptScore W3017625823C175708663 @default.
- W3017625823 hasConceptScore W3017625823C178516000 @default.
- W3017625823 hasConceptScore W3017625823C178790620 @default.