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• W3018272851 abstract "Poor rate and cycling performance are the most critical drawbacks for Si-based anodes on account of their inferior conductivity and colossal volumetric expansion during lithiation/delithiation. Here we report the fabrication of structurally-integrated urchin-like Si anode, which provides prominent structural stability and distinguished electron and ion transmission pathways for lithium storage. The inexpensive solid Si waste from organosilane industry after acid-washed and further ball-milling serves as the pristine Si-source in this work. Carbon nanotubes (CNTs) are in-situ grown outside Si microparticles, resulting in an urchin-like structure (Si/CNTs). The optimized Si/CNTs presents ascendant invertible capacity and rate performance, achieving up to 920 mAh g-1 beyond 100 cycles at 100 mA g -1, and a capacity of 606.2 mAh g-1 at 1 A g -1 after long cycling for 1000 cycles. The proposed scalable synthesis can be adopted to advance the performance of other electrode materials with inferior conductivity and enormous volume expansions during cycling." @default.
• W3018272851 created "2020-05-01" @default.
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• W3018272851 date "2020-09-01" @default.
• W3018272851 modified "2023-10-16" @default.
• W3018272851 title "Low-cost urchin-like silicon-based anode with superior conductivity for lithium storage applications" @default.
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• W3018272851 doi "https://doi.org/10.1016/j.jcis.2020.04.082" @default.
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