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- W3018586314 endingPage "136276" @default.
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- W3018586314 abstract "In this study, cobalt is electrodeposited within solvothermally grown thin films of a zirconium-based metal–organic framework, MOF-808, to obtain electrochemically active cobalt confined in the pore of MOF-808 crystals. With the help of the highly porous but electrically insulating MOF-808 thin film and a step-wise electrodepositing technique, cobalt can be mainly deposited within the pore of MOF-808 crystals. The resulting [email protected] thin film is applied for electrochemical H2O2 sensor in aqueous electrolytes, and its electrocatalytic activity toward H2O2 significantly outperforms that of the electrodeposited cobalt on a bare substrate. The electrochemical behavior of [email protected] thin films and the corresponding electrocatalytic mechanism toward H2O2 are investigated. The material is further used for amperometric H2O2 detection, and a sensitivity, limit of detection, and linear range of 382.27 μA/mM-cm2, 1.3 μM, and 10–450 μM can be achieved, respectively." @default.
- W3018586314 created "2020-05-01" @default.
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- W3018586314 date "2020-07-01" @default.
- W3018586314 modified "2023-10-18" @default.
- W3018586314 title "Electrodeposition of pore-confined cobalt in metal–organic framework thin films toward electrochemical H2O2 detection" @default.
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- W3018586314 doi "https://doi.org/10.1016/j.electacta.2020.136276" @default.
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