Matches in SemOpenAlex for { <https://semopenalex.org/work/W3018719310> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W3018719310 abstract "The core size of the porphyrin macrocycles was closely related to their stability of the different electron structure in the central metal ion. Cobalt(II) ions can undergo a conversion in electron configurations upon N₄ core contraction of 0.05 A in nonplanar porphyrins, and these ions still maintain low spin forms after and before conversion. The structural fine-tuning can induce the appearance of a cross-hybrid stage [d(ₓ₂₋y²)sp² ↔ d(z₂)sp²] based on quadrilateral coordination of the planar core. The results indicate that the configuration conversion plays a key role in electron transfer in redox catalysis involving cobalt complexes. The electronic properties of six monostrapped cobalt(II) porphyrins were investigated by spectral, paramagnetic, and electrochemical methods. The macrocyclic deformations and size parameters of Co-containing model compounds were directly obtained from their crystal structures." @default.
- W3018719310 created "2020-05-01" @default.
- W3018719310 creator A5070538645 @default.
- W3018719310 creator A5071731927 @default.
- W3018719310 creator A5074129721 @default.
- W3018719310 creator A5076513019 @default.
- W3018719310 creator A5087102112 @default.
- W3018719310 date "2015-01-01" @default.
- W3018719310 modified "2023-09-22" @default.
- W3018719310 title "Fine-Tuning of Electronic Structure of Cobalt(II) Ion in Nonplanar Porphyrins and Tracking of a Cross-Hybrid Stage: Implications for the Distortion of Natural Tetrapyrrole Macrocycles B" @default.
- W3018719310 hasPublicationYear "2015" @default.
- W3018719310 type Work @default.
- W3018719310 sameAs 3018719310 @default.
- W3018719310 citedByCount "0" @default.
- W3018719310 crossrefType "journal-article" @default.
- W3018719310 hasAuthorship W3018719310A5070538645 @default.
- W3018719310 hasAuthorship W3018719310A5071731927 @default.
- W3018719310 hasAuthorship W3018719310A5074129721 @default.
- W3018719310 hasAuthorship W3018719310A5076513019 @default.
- W3018719310 hasAuthorship W3018719310A5087102112 @default.
- W3018719310 hasConcept C115624301 @default.
- W3018719310 hasConcept C123669783 @default.
- W3018719310 hasConcept C145148216 @default.
- W3018719310 hasConcept C147789679 @default.
- W3018719310 hasConcept C17525397 @default.
- W3018719310 hasConcept C178790620 @default.
- W3018719310 hasConcept C179104552 @default.
- W3018719310 hasConcept C181199279 @default.
- W3018719310 hasConcept C185592680 @default.
- W3018719310 hasConcept C199164860 @default.
- W3018719310 hasConcept C2777710969 @default.
- W3018719310 hasConcept C2779480358 @default.
- W3018719310 hasConcept C515602321 @default.
- W3018719310 hasConcept C52859227 @default.
- W3018719310 hasConcept C75473681 @default.
- W3018719310 hasConcept C8010536 @default.
- W3018719310 hasConceptScore W3018719310C115624301 @default.
- W3018719310 hasConceptScore W3018719310C123669783 @default.
- W3018719310 hasConceptScore W3018719310C145148216 @default.
- W3018719310 hasConceptScore W3018719310C147789679 @default.
- W3018719310 hasConceptScore W3018719310C17525397 @default.
- W3018719310 hasConceptScore W3018719310C178790620 @default.
- W3018719310 hasConceptScore W3018719310C179104552 @default.
- W3018719310 hasConceptScore W3018719310C181199279 @default.
- W3018719310 hasConceptScore W3018719310C185592680 @default.
- W3018719310 hasConceptScore W3018719310C199164860 @default.
- W3018719310 hasConceptScore W3018719310C2777710969 @default.
- W3018719310 hasConceptScore W3018719310C2779480358 @default.
- W3018719310 hasConceptScore W3018719310C515602321 @default.
- W3018719310 hasConceptScore W3018719310C52859227 @default.
- W3018719310 hasConceptScore W3018719310C75473681 @default.
- W3018719310 hasConceptScore W3018719310C8010536 @default.
- W3018719310 hasLocation W30187193101 @default.
- W3018719310 hasOpenAccess W3018719310 @default.
- W3018719310 hasPrimaryLocation W30187193101 @default.
- W3018719310 hasRelatedWork W1975668175 @default.
- W3018719310 hasRelatedWork W1979873305 @default.
- W3018719310 hasRelatedWork W1986468006 @default.
- W3018719310 hasRelatedWork W2006381296 @default.
- W3018719310 hasRelatedWork W2010058878 @default.
- W3018719310 hasRelatedWork W2019219584 @default.
- W3018719310 hasRelatedWork W2045478333 @default.
- W3018719310 hasRelatedWork W2052620687 @default.
- W3018719310 hasRelatedWork W2062739386 @default.
- W3018719310 hasRelatedWork W2089465204 @default.
- W3018719310 hasRelatedWork W2090261676 @default.
- W3018719310 hasRelatedWork W2135072233 @default.
- W3018719310 hasRelatedWork W2164024940 @default.
- W3018719310 hasRelatedWork W2184513401 @default.
- W3018719310 hasRelatedWork W2789787936 @default.
- W3018719310 hasRelatedWork W2949112800 @default.
- W3018719310 hasRelatedWork W2950225385 @default.
- W3018719310 hasRelatedWork W3013626087 @default.
- W3018719310 hasRelatedWork W3197521947 @default.
- W3018719310 hasRelatedWork W908902189 @default.
- W3018719310 isParatext "false" @default.
- W3018719310 isRetracted "false" @default.
- W3018719310 magId "3018719310" @default.
- W3018719310 workType "article" @default.