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• W3019004009 startingPage "2000958" @default.
• W3019004009 abstract "Constructing 2D heterostructure materials by stacking different 2D materials can combine the merits of the individual building blocks while eliminating their shortcomings. Dichalcogenides are attractive anodes for potassium-ion batteries (KIBs) due to their high theoretical capacity. However, the practical application of dichalcogenide is greatly hampered by the poor electrochemical performance due to sluggish kinetics of K+ insertion and the electrode structure collapse resulting from the large K+ insertion. Herein, heterostructures of 2D molybdenum dichalcogenide on 2D nitrogen-doped carbon (MoS2 , MoSe2 -on-NC) are prepared to boost their potassium storage performance. The unique 2D heterostructures possess built-in heterointerfaces, facilitating K+ diffusion. The robust chemical bonds (CS, CSe, CMo bonds) enhance the mechanical strength of electrodes, thus suppressing the volume expansion. The 2D N-doped carbon nanosheets interconnected as a 3D structure offer a fast diffusion path for electrons. Benefitting from these merits, both the MoS2 -on-NC and the MoSe2 -on-NC exhibit unprecedented cycle life. Moreover, the electrochemical reaction mechanism of MoSe2 is revealed during the process of potassiation and depotassiation." @default.
• W3019004009 created "2020-05-01" @default.
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• W3019004009 date "2020-04-22" @default.
• W3019004009 modified "2023-10-18" @default.
• W3019004009 title "Heterostructures of 2D Molybdenum Dichalcogenide on 2D Nitrogen‐Doped Carbon: Superior Potassium‐Ion Storage and Insight into Potassium Storage Mechanism" @default.
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• W3019004009 doi "https://doi.org/10.1002/adma.202000958" @default.
• W3019004009 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32323393" @default.
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